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Solar!

Solar

Active solar

Solar trackers may be driven by active or passive solar technologyActive solar technologies are employed to convert solar energy into usable heat, cause air-movement for ventilation or cooling, or store heat for future use. Active solar uses electrical or mechanical equipment, such as pumps and fans, to increase the usable heat in a system. Solar energy collection and utilization systems that do not use external energy, like a solar chimney, are classified as passive solar technologies.

Solar hot water systems, except those based on the thermosiphon, use pumps or fans to circulate water, an anti-freeze mixture, or air through solar collectors, and are therefore classified under active solar technology. The solar collectors can be nonconcentrating or 'flat-plate', or of various concentrating designs. Most solar-thermal collectors have fixed mounting, but can have a higher performance if they track the path of the sun through the sky. Solar trackers, used to orient photovoltaic arrays, may be driven by either passive or active technology.

Solar technology comparison

Active solar-thermal systems, via small pumps or fans, can have significantly higher solar savings fractions than passive solar technologies due to greatly-enhanced heat transfer and transport. An interesting hybrid approach is to use photovoltaics to power pumps or fans. A computer analysis, using thermodynamics and heat transfer software, can be used to compare the performance of various active and passive solar thermal strategies

Passive solar

Solar panels are used in passive and active solar hot water systemsPassive solar technologies are means of using sunlight for useful energy without use of active mechanical systems (as contrasted to active solar). Such technologies convert sunlight into usable heat (water, air, thermal mass), cause air-movement for ventilating, or store heat for future use, with little use of other energy sources. A common example is a solarium on the equator-side of a building. Passive cooling is the use of the same design principles to reduce summer cooling requirements.

Technologies that use a significant amount of conventional energy to power pumps or fans are active solar technologies. Some passive systems use a small amount of conventional energy to control dampers, shutters, night insulation, and other devices that enhance solar energy collection, storage, use, and reduce undesirable heat transfer.

Passive solar technologies include direct and indirect solar gain for space heating, solar water heating systems based on the thermosiphon, use of thermal mass and phase-change materials for slowing indoor air temperature swings, solar cookers, the solar chimney for enhancing natural ventilation, and earth sheltering.

More widely, passive solar technologies include the solar furnace and solar forge, but these typically require some external energy for aligning their concentrating mirrors or receivers, and historically have not proven to be practical or cost effective for wide-spread use. 'Low-grade' energy needs, such as space and water heating, have proven, over time, to be better applications for passive use of solar energy.

Advantages and comparisons to active solar

Passive solar systems have little to no operating costs, often have low maintenance costs, and emit no greenhouse gases in operation. They do, however, need to be optimized to yield the best performance and economics. Energy conservation reduces the needed size of any renewable or conventional energy system, and greatly enhances the economics, so it must be performed first. Passive solar technologies often yield high solar savings fractions, especially for space heating; when combined with active solar technologies or photovoltaics (for example, to power pumps or fans), even higher conventional energy savings can be achieved.

Passive solar building design

Passive solar buildings aim to maintain interior thermal comfort throughout the sun's daily and annual cycles whilst reducing the requirement for active heating and cooling systems. Passive solar building design is one part of green building design, and does not include active systems such as mechanical ventilation or photovoltaics.

Solar As a science

The scientific basis for passive solar building design has been developed from a combination of climatology, thermodynamics (particularly heat transfer), and human thermal comfort (for buildings to be inhabited by humans). Specific attention is directed to the site and location of the dwelling, the prevailing climate, design and construction, solar orientation, placement of glazing-and-shading elements, and incorporation of thermal mass. While these considerations may be directed to any building, achieving an ideal solution requires careful integration of these principles. Modern refinements through computer modeling and application of other technology can achieve significant energy savings without necessarily sacrificing functionality or creative aesthetics.

The solar path in passive design

The ability to achieve these goals simultaneously is fundamentally dependent on the seasonal variations in the sun's path throughout the day

This occurs as a result of the inclination of the earth's axis of rotation in relation to its orbit. The sun path is unique for any given latitude. Generally the sun will appear to rise in the east and set in the west.

In Northern Hemisphere non-tropical latitudes farther than 23.5 degrees from the equator:

The sun will reach its highest point toward the South (in the direction of the equator) As winter solstice approaches, the angle at which the sun rises and sets progressively moves further toward the South and the daylight hours will become shorter

The opposite is noted in summer where the sun will rise and set further toward the North and the daylight hours will lengthen

The converse is observed in the Southern Hemisphere, but the sun rises to the east and sets toward the west regardless of which hemisphere you are in.

In equatorial regions at less than 23.5 degrees, the position of the sun at solar noon will oscillate from north to south and back again during the year.

In regions closer than 23.5 degrees from either north-or-south pole, during summer the sun will trace a complete circle in the sky without setting whilst it will never appear above the horizon six months later, during the height of winter.

The 47-degree difference in the altitude of the sun at solar noon between winter and summer forms the basis of passive solar design. This information is combined with local climatic data (degree day) heating and cooling requirements to determine at what time of the year solar gain will be beneficial for thermal comfort, and when it should be blocked with shading. By strategic placement of items such as glazing and shading devices, the percent of solar gain entering a building can be controlled throughout the year.

One passive solar sun path design problem is that the sun is in the same relative position six weeks before, and six weeks after, the solstice, BUT due to "thermal lag" from the thermal mass of the Earth, the temperature and solar gain requirements are quite different before-and-after the summer-and-winter solstice. Movable shutters, shades, shade screen, or window quilts can accommodate day-to-day and hour-to-hour solar gain and insulation requirements.

Careful arrangement of rooms completes the passive solar design. A common recommendation for residential dwellings is to place living areas facing solar noon and sleeping quarters on the opposite side. A heliodon is a traditional movable light device used by architects and designers to help model sun path effects. In modern times, 3D computer graphics can visually simulate this data, and calculate performance predictions.

Passive solar thermodynamic principles

Personal thermal comfort is a function of ambient air temperature, mean radiant temperature, air movement (wind chill, turbulence) and relative humidity (affecting human evaporative cooling). Heat transfer in buildings occurs through convection, conduction, and thermal radiation through roof, walls, floor and windows.

Solar Convective heat transfer

Convective heat transfer can be beneficial or detrimental. Uncontrolled air infiltration from poor weatherisation / weatherstripping / draught-proofing can contribute up to 40% of heat loss during winter, however strategic placement of operable windows or vents can enhance convection, cross-ventilation, and summer cooling when the outside air is of a comfortable temperature and relative humidity. Filtered energy recovery ventilation systems may be useful to eliminate undesirable humidity, dust, pollen, and microorganisms in unfiltered ventilation air.

Natural convection causing rising warm air and falling cooler air can result in an uneven stratification of heat. This may cause uncomfortable variations in temperature in the upper and lower conditioned space, serve as a method of venting hot air, or be designed in as a natural-convection air-flow loop for passive solar heat distribution and temperature equalization. Natural human cooling by perspiration and evaporation may be facilitated through natural or forced convective air movement by fans, but ceiling fans can disturb the stratified insulating air layers at the top of a room, and accelerate heat transfer from and hot attic, or through near by windows. In addition, high relative humidity inhibits evaporative cooling by humans.

Solar Radiative heat transfer

The main source of heat transfer is radiant energy, and the primary source is the sun. Solar radiation occurs predominantly through the roof and windows (but also through walls). Thermal radiation moves from a warmer surface to a cooler one. Roofs receive the majority of the solar radiation delivered to a house. A cool roof, or green roof in addition to a radiant barrier can help prevent your attic from becoming hotter than the peak summer outdoor air temperature (see albedo, absorptivity, emissivity, and reflectivity).

Windows are a ready and predictable site for thermal radiation. Energy from radiation can move into a window in the day time, and out of the same window at night. Radiation uses photons to transmit electromagnetic waves through a vacuum, or translucent medium. Solar heat gain can be significant even on cold clear days. Solar heat gain through windows can be reduced by insulated glazing, shading, and orientation. Windows are particularly difficult to insulate compared to roof and walls. Convective heat transfer through and around window coverings also degrade its insulation properties. When shading windows, external shading is more effective at reducing heat gain than internal window coverings.

Western and eastern sun can provide warmth and lighting, but are vulnerable to overheating in summer if not shaded. In contrast, the low midday sun readily admits light and warmth during the winter, but can be easily shaded with appropriate length overhangs or angled louvres during summer. The amount of radiant heat received is related to the location latitude, altitude, cloud cover, and seasonal / hourly angle of incidence (see Sun path and Lambert's cosine law).

Another passive solar design principle is that thermal energy can be stored in certain building materials and released again when heat gain eases to stabilize diurnal (day/night) temperature variations. The complex interaction of thermodynamic principles can be counterintuitive for first-time designers. Precise computer modeling can help avoid costly construction experiments.

Solar Site specific considerations during design

Latitude and sun path

Seasonal variations in solar gain e.g. cooling or heating degree days, solar insolation, humidity

Diurnal variations in temperature

Micro-climate details related to breezes, humidity, vegetation and land contour

Obstructions / Over-shadowing - to solar gain or local cross-winds

Solar Design elements for residential buildings in temperate climates

Orienting the building to face the equator (or a few degrees to the East to capture the morning sun)

Extending the building dimension along the east/west axis

Adequately-sizing windows to face the midday sun in the winter, and be shaded in the summer.

Minimising windows on other sides, especially western windows

Erecting correctly-sized, latitude-specific overhangs, or shading elements (shrubbery, trees, trellises, fences, shutters, etc.)

Using the appropriate amount and type of insulation including radiant barriers and bulk insulation to minimise seasonal excessive heat gain or loss

Using thermal mass to store excess solar energy during the winter day (which is then re-radiated during the night) The precise amount of equator-facing glass and thermal mass should be based on careful consideration of latitude, altitude, climatic conditions, and heating/cooling degree day requirements.

Factors that can degrade thermal performance:

Deviation from ideal orientation and north/south/east/west aspect ratio Excessive glass area ('over-glazing') resulting in overheating (also resulting in glare and fading of soft furnishings) and heat loss when ambient air temperatures fall

Installing glazing where solar gain during the day and thermal losses during the night cannot be controlled easily e.g. West-facing, angled glazing, skylights.

Thermal losses through non-insulated or unprotected glazing

Lack of adequate shading during seasonal periods of high solar gain (especially on the West wall)

Incorrect application of thermal mass to modulate daily temperature variations Open staircases leading to unequal distribution of warm air between upper and lower floors as warm air rises

High building surface area to volume - Too many corners

Inadequate weatherization leading to high air infiltration

Lack of, or incorrectly-installed, radiant barriers during the hot season. (See also cool roof and green roof)

Insulation materials that are not matched to the main mode of heat transfer (e.g. undesirable convective/conductive/radiant heat transfer)

Key passive solar building design concepts

There are four primary passive solar energy configurations:

direct solar gain

indirect solar gain

isolated solar gain

passive cooling

Direct solar gain

Elements of passive solar design, shown in a direct gain applicationDirect gain attempts to control the amount of direct solar radiation reaching the living space. The cost effectiveness of these configurations are currently being investigated in great detail and are demonstrating promising results.

Indirect solar gain

Indirect gain attempts to control solar radiation reaching an area adjacent but not part of the living space. Heat enters the building through windows and is captured and stored in thermal mass (e.g water tank, masonry wall) and slowly transmitted indirectly to the building through conduction and convection. Efficiency can suffer from slow response (thermal lag) and heat losses at night. Other issues include the cost of insulated glazing and developing effective systems to redistribute heat throughout the living area.

Examples:

Trombe walls

Water walls

Roof ponds

Isolated solar gain

Isolated gain involves utilizing solar energy to passively move heat from or to the living space using a fluid, such as water or air by natural convection or forced convection. Heat gain can occur through a sunspace, solarium or solar closet. These areas may also be employed usefully as a greenhouse or drying cabinet. An equator-side sun room may have its exterior windows higher than the windows between the sun room and the interior living space, to allow the low winter sun to penetrate to the cold side of adjacent rooms. Glass placement and overhangs prevent solar gain during the summer. Earth cooling tubes or other passive cooling techniques can keep a solarium cool in the summer.

Measures should be taken to reduce heat loss at night e.g. window coverings or movable window insulation

Examples:

Thermosiphon

Barra system

Double envelope house

Thermal buffer zone

Solar space heating system

Solar chimney

Other considerations on Solar

Solar Insulation

Thermal insulation or superinsulation (type, placement and amount) assists in significantly reducing unwanted heat transfer.

Special glazing Solar systems and window coverings

The effectiveness of direct solar gain systems is significantly enhanced by insulative (e.g. double glazing), spectrally-selective glazing (low-e), or movable window insulation (window quilts, bifold interior insulation shutters, shades, etc.).

Generally, Equator-facing windows should not employ glazing coatings that inhibit solar gain.

There is extensive use of super-insulated windows in the German Passive House standard. Selection of different spectrally-selective window coating depends on the ratio of heating versus cooling degree days for the design location.

Solar Glazing selection

Solar Equator-facing glass

The requirement for vertical equator-facing glass is different than for the other three sides of a building. Reflective window coatings and multiple panes of glass can reduce useful solar gain. However, direct-gain systems are more dependent on double or triple glazing to reduce heat loss. Indirect-gain and isolated-gain configurations may still be able to function effectively with only single-pane glazing. Nevertheless, the optimal cost-effective solution is both location and system dependent.

Solar Roof-angle glass and Skylights

Sloping roof-angled glass is difficult to shade and insulate without sophisticated movable systems. In hot climates with significant degree day cooling requirements, it can create a summer solar furnace (from the Ancient Greek / Roman term "heliocaminus").

Roof-angled glass or skylights are not optimally placed to receive low-angled winter sun. At the same time, they are the site of heat loss during winter from the buoyant warm air that rises. As a result, they will increase heating and cooling energy requirements, which exceeds the benefit of daylight energy consumption reduction compared to more energy-efficient lighting systems such as light tubes.

Transparent glass and plastic have little structural strength. Vertically, they bear their own weight because only the thickness is subject to gravity. As the angle tilts from vertical, an increased area (the sloped cross-section) must resist gravity. Glass is brittle - It does not flex much before breaking - To counteract this, you must increase thickness, or structural supports - Both increase overall cost, and reduce solar gain potential. Sloped glazing is exposed to the weather, leaks, hail, ice-and-snow load, wind, and material failure. Excess solar gain, harsh lighting, and undesirable heat transfer thru sloped glass are difficult to control. Therefore, vertical glazing is the overall best option for sunspaces.

Solar Angle of incident radiation

The amount of solar gain transmitted through glass is also affected by the angle of the incident solar radiation. Sunlight striking glass within 20 degrees of perpendicular is mostly transmitted through the glass, whereas sunlight at more than 35 degrees from perpendicular is mostly reflected

All of these factors can be modeled more precisely with a photographic light meter and a heliodon or optical bench, which can quantify the ratio of reflectivity to transmissivity, based on angle of incidence.

Alternatively, passive solar computer software can determine the impact of sun path, and cooling-and-heating degree days on energy performance. Regional climatic conditions are often available from local weather services.

Solar Operable shading and insulation devices

A design with too much equator-facing glass can result in excessive winter, spring, or fall day heating, uncomfortably-bright living spaces at certain times of the year, and excessive heat transfer on winter nights and summer days.

Although the sun is at the same altitude 6-weeks before and after the solstice, the heating and cooling requirements before and after the solstice are significantly different. Heat storage on the Earth's surface causes "thermal lag." Variable cloud cover influences solar gain potential. This means that latitude-specific fixed window overhangs, while important, are not a complete seasonal solar gain control solution.

Control mechanisms (such as manual-or-motorized interior insulated drapes, shutters, exterior roll-down shade screens, or retractable awnings) can compensate for differences caused by thermal lag or cloud cover, and help control daily / hourly solar gain requirement variations. Home automation systems that monitor temperature, sunlight, time of day, and room occupancy can precisely control motorized window-shading-and-insulation devices.

Exterior Solar finishes

Materials and colors can be chosen to reflect or absorb solar thermal energy. See "Cool Colors" by Lawrence Berkeley National Laboratory and Oak Ridge National Laboratory

Solar Landscaping

Energy-efficient landscaping materials, including the use of trees, plants, hedges, or a trellis (agriculture), can be used to selectively create summer shading (particularly in the case of deciduous plants that give up their leaves in the winter), and also to create winter wind chill shelter. Xeriscaping is used to reduce or eliminate the need for energy-and-water-intensive irrigation.

Other passive solar principles

Passive solar lighting

Passive solar lighting techniques attempt to take advantage of natural illumination and reduce reliance on artificial lighting systems.

This can be achieved by careful building design and placement of window sections. Other creative solutions involve the use of reflecting surfaces to admit daylight into the interior of a building such as a solar light tube, or light shelf. Window sections should be adequately sized without resulting in over-illumination.

Another major issue for many window systems is that they can be potentially vulnerable sites of excessive thermal gain or heat loss. Whilst high mounted clerestory window and traditional skylights can introduce daylight in poorly-orientated sections of a building, unwanted heat transfer may be hard to control Thus, energy that is saved by reducing artificial lighting is often more than offset by the energy required for operating HVAC systems to maintain thermal comfort.

Various methods can be employed to address this including but not limited to window coverings, insulated glazing and novel materials such as aerogel semi-transparent insulation, optical fiber embedded in walls or roof, or hybrid solar lighting at Oak Ridge National Laboratory.

Passive solar water heating

There are many ways to use solar thermal energy to heat water for domestic use. Different active-and-passive solar hot water technologies have different location-specific economic cost benefit analysis implications.

Fundamental passive solar hot water heating involves no pumps or anything electrical. It is very cost effective in climates that do not have lengthy sub-freezing, or very-cloudy, weather conditions. Other active solar water heating technologies, etc. may be more appropriate for some locations.

It is possible to have active solar hot water which is also capable of being "off grid" and qualifies as sustainable. This is done by the use of a photovoltaic cell which uses energy from the sun to power the pumps.

Solar Design tools

Traditionally a heliodon was used to simulate the altitude and azimuth of the sun shining on a model building at any time of any day of the year. In modern times, computer programs can model this phenomenon and integrate local climate data (including site impacts such as overshadowing and physical obstructions) to predict the solar gain potential for a particular building design over the course of a year. This provides the designer the ability to evaluate design elements and orientation prior to building works commencing. Energy performance optimization normally requires an iterative-refinement design-and-evaluate process.

Solar Levels of application

Pragmatic Solar

Many detached suburban houses can achieve reductions in heating expense without obvious changes to their appearance, comfort or usability. This is done using good siting and window positioning, small amounts of thermal mass, with good-but-conventional insulation, weatherization, and an occasional supplementary heat source, such as a central radiator connected to a (solar) water heater. Sunrays may fall on a wall during the daytime and raise the temperature of its thermal mass. This will then radiate heat into the building in the evening. This can be a problem in the summer, especially on western walls in areas with high degree day cooling requirements. External shading, or a radiant barrier plus air gap, may be used to reduce undesirable summer solar gain.

Annualised Solar

An extension of the "passive solar" approach to diurnal solar capture and storage ("short-cycle passive solar"). Other experimental designs attempt to capture warm-season solar heat, convey it to a seasonal thermal store for use months later during the cool or cold season ("annualised passive solar.") Increased storage is achieved by employing large amounts of thermal mass or earth coupling. Anecdotal reports suggest they can be effective but no formal study has been conducted to demonstrate their superiority.

Examples:

Passive Annual Heat Storage (PAHS) - by John Hait

Annualized Geothermal Solar (AGS) heating - by Don Stephen

Earthed-roof

Minimum Solar machinery

A "purely passive" solar-heated house would have no mechanical furnace unit, relying instead on energy captured from sunshine, only supplemented by "incidental" heat energy given off by lights, computers, and other task-specific appliances (such as those for cooking, entertainment, etc.), showering, people and pets. The use of natural convection air currents (rather than mechanical devices such as fans) to circulate air is related, though not strictly solar design.

Passive solar building design sometimes uses limited electrical and mechanical controls to operate dampers, insulating shutters, shades, awnings, or reflectors. Some systems enlist small fans or solar-heated chimneys to improve convective air-flow. A reasonable way to analyse these systems is by measuring their coefficient of performance. A heat pump might use 1 J for every 4 J it delivers giving a COP of 4. A system that only uses a 30 W fan to more-evenly distribute 10 kW of solar heat through an entire house would have a COP of 300.

Zero Solar Energy Building

Passive solar building design is often a foundational element of a cost-effective zero energy building. Although a ZEB uses multiple passive solar building design concepts, a ZEB is usually not purely passive, having active mechanical renewable energy generation systems such as: wind turbine, photovoltaics, micro hydro, geothermal, and other emerging alternative energy sources.

Solar cell

It has been suggested that High efficiency solar cells be merged into this article or section. (Discuss)

A solar cell or photovoltaic cell is a wide area electronic device that converts solar energy into electricity by the photovoltaic effect. Photovoltaics is the field of technology and research related to the application of solar cells as solar energy. Sometimes the term solar cell is reserved for devices intended specifically to capture energy from sunlight, while the term photovoltaic cell is used when the source is unspecified. Assemblies of cells are used to make solar modules, or photovoltaic arrays.

Solar cells have many applications. Cells are used for powering small devices such as electronic calculators. Photovoltaic arrays generate a form of renewable electricity, particularly useful in situations where electrical power from the grid is unavailable such as in remote area power systems, Earth-orbiting satellites and space probes, remote radiotelephones and water pumping applications. Photovoltaic electricity is also increasingly deployed in grid-tied electrical systems. Similar devices intended to capture energy from other sources include thermophotovoltaic cells, betavoltaics cells, and optoelectric nuclear batteries.

Solar History

The term "photovoltaic" comes from the Greek f?? (phos) meaning "light", and "voltaic", meaning electrical, from the name of the Italian physicist Volta, after whom kevin is a unit of electrical potential, the volt, is named. The term "photo-voltaic" has been in use in English since 1849.

The photovoltaic effect was first recognized in 1839 by French physicist A. E. Becquerel. However, it was not until 1883 that the first solar cell was built, by Charles Fritts, who coated the semiconductor selenium with an extremely thin layer of gold to form the junctions. The device was only around 1% efficient. Russell Ohl patented the modern solar cell in 1946 (U.S. Patent 2,402,662 , "Light sensitive device"). Sven Ason Berglund had a prior patent concerning methods of increasing the capacity of photosensitive cells. The modern age of solar power technology arrived in 1954 when Bell Laboratories, experimenting with semiconductors, accidentally found that silicon doped with certain impurities was very sensitive to light.

This resulted in the production of the first practical solar cells with a sunlight energy conversion efficiency of around 6 percent. The first spacecraft to use solar panels was the US satellite Vanguard 1, launched in March 1958 with solar cells made by Hoffman Electronics. This milestone created interest in producing and launching a geostationary communications satellite, in which solar energy would provide a viable power supply. This was a crucial development which stimulated funding from several governments into research for improved solar cells.

In 1970 the first highly effective GaAs heterostructure solar cells were created by Zhores Alferov and his team in the USSR. Metal Organic Chemical Vapor Deposition (MOCVD, or OMCVD) production equipment was not developed until the early 1980s, limiting the ability of companies to manufacture the GaAs solar cell. In the United States, the first 17% efficient air mass zero (AM0) single-junction GaAs solar cells were manufactured in production quantities in 1988 by Applied Solar Energy Corporation (ASEC). The "dual junction" cell was accidentally produced in quantity by ASEC in 1989 as a result of the change from GaAs on GaAs substrates to GaAs on Germanium (Ge) substrates. The accidental doping of Ge with the GaAs buffer layer created higher open circuit voltages, demonstrating the potential of using the Ge substrate as another cell. As GaAs single-junction cells topped 19% AM0 production efficiency in 1993, ASEC developed the first dual junction cells for spacecraft use in the United States, with a starting efficiency of approximately 20%. These cells did not utilize the Ge as a second cell, but used another GaAs-based cell with different doping. Eventually GaAs dual junction cells reached production efficiencies of about 22%. Triple Junction solar cells began with AM0 efficiencies of approximately 24% in 2000, 26% in 2002, 28% in 2005, and in 2007 have evolved to a 30% AM0 production efficiency, currently in qualification.

In 2007, two companies in the United States, Emcore Photovoltaics and Spectrolab, produce 95% of the world's Triple Junction solar cells which have a commercial efficiency of 38%. In 2006 Spectrolab's cells achieved 40.7% efficiency in lab testing.

Scientists at the U.S. Department of Energy's National Renewable Energy Laboratory (NREL) have set a world record in solar cell efficiency with a photovoltaic device that converts 40.8 percent of the light that hits it into electricity. This is the highest confirmed efficiency of any photovoltaic device to date.

Three generations of solar cells

Solar Cells are classified into three generations which indicates the order of which each became prominent. At present there is concurrent research into all three generations while the first generation technologies are most highly presented in commercial production, accounting for 89.6% of 2007 production.

First Solar Generation

First generation cells consist of large-area, high quality and single junction devices. First Generation technologies involve high energy and labour inputs which prevent any significant progress in reducing production costs. Single junction silicon devices are approaching the theoretical limiting efficiency of 33% and achieve cost parity with fossil fuel energy generation after a payback period of 5-7 years.

Second Solar Generation

Second generation materials have been developed to address energy requirements and production costs of solar cells. Alternative manufacturing techniques such as vapour deposition and electroplating are advantageous as they reduce high temperature processing significantly. It is commonly accepted that as manufacturing techniques evolve production costs will be dominated by constituent material requirements, whether this be a silicon substrate, or glass cover. Second generation technologies are expected to gain market share in 2008.

The most successful second generation materials have been cadmium telluride (CdTe), copper indium gallium selenide, amorphous silicon and micromorphous silicon. These materials are applied in a thin film to a supporting substrate such as glass or ceramics reducing material mass and therefore costs. These technologies do hold promise of higher conversion efficiencies, particularly CIGS-CIS, DSC and CdTe offers significantly cheaper production costs.

Among major manufacturers there is certainly a trend toward second generation technologies however commercialisation of these technologies has proven difficult. In 2007 First Solar produced 200 MW of CdTe solar cells making it the fifth largest producer of solar cells in 2007 and the first ever to reach the top 10 from production of second generation technologies alone. Wurth Solar commercialised its CIS technology in 2007 producing 15 MW. Nanosolar commercialised its CIGS technology in 2007 with a production capacity of 430 MW for 2008 in the USA and Germany.

In 2007 CdTe production represented 4.7% of total market share, thin-film silicon 5.2% and CIGS 0.5%.

Third Solar Generation

Third generation technologies aim to enhance poor electrical performance of second generation (thin-film technologies) while maintaining very low production costs. Current research is targeting conversion efficiencies of 30-60% while retaining low cost materials and manufacturing techniques. There are a few approaches to achieving these high efficiencies:

Multijunction photovoltaic cell.

Modifying incident spectrum (concentration).

Use of excess thermal generation to enhance voltages or carrier collection.

Solar Applications and implementations

Polycrystaline PV cells laminated to backing material in a PV module

Polycrystalline PV cells

Solar cells are often electrically connected and encapsulated as a module. PV modules often have a sheet of glass on the front (sun up) side , allowing light to pass while protecting the semiconductor wafers from the elements (rain, hail, etc.). Solar cells are also usually connected in series in modules, creating an additive voltage. Connecting cells in parallel will yield a higher current. Modules are then interconnected, in series or parallel, or both, to create an array with the desired peak DC voltage and current.

The power output of a solar array is measured in watts or kilowatts. In order to calculate the typical energy needs of the application, a measurement in watt-hours, kilowatt-hours or kilowatt-hours per day is often used. A common rule of thumb is that average power is equal to 20% of peak power, so that each peak kilowatt of solar array output power corresponds to energy production of 4.8 kWh per day.

To make practical use of the solar-generated energy, the electricity is most often fed into the electricity grid using inverters (grid-connected PV systems); in stand alone systems, batteries are used to store the energy that is not needed immediately.

Solar Theory

Solar Simple explanation

Photons in sunlight hit the solar panel and are absorbed by semiconducting materials, such as silicon. Electrons (negatively charged) are knocked loose from their atoms, allowing them to flow through the material to produce electricity. Due to the special composition of solar cells, the electrons are only allowed to move in a single direction. The complementary positive charges that are also created (like bubbles) are called holes and flow in the direction opposite of the electrons in a silicon solar panel. An array of solar panels converts solar energy into a usable amount of direct current (DC) electricity.

Photogeneration of Solar charge carriers

When a photon hits a piece of silicon, one of three things can happen:

the photon can pass straight through the silicon this (generally) happens for lower energy photons, the photon can reflect off the surface,

the photon can be absorbed by the silicon, if the photon energy is higher than the silicon band gap value. This generates an electron-hole pair and sometimes heat, depending on the band structure.

When a photon is absorbed, its energy is given to an electron in the crystal lattice. Usually this electron is in the valence band, and is tightly bound in covalent bonds between neighboring atoms, and hence unable to move far. The energy given to it by the photon "excites" it into the conduction band, where it is free to move around within the semiconductor. The covalent bond that the electron was previously a part of now has one fewer electron this is known as a hole. The presence of a missing covalent bond allows the bonded electrons of neighboring atoms to move into the "hole," leaving another hole behind, and in this way a hole can move through the lattice. Thus, it can be said that photons absorbed in the semiconductor create mobile electron-hole pairs.

A photon need only have greater energy than that of the band gap in order to excite an electron from the valence band into the conduction band. However, the solar frequency spectrum approximates a black body spectrum at ~6000 K, and as such, much of the solar radiation reaching the Earth is composed of photons with energies greater than the band gap of silicon. These higher energy photons will be absorbed by the solar cell, but the difference in energy between these photons and the silicon band gap is converted into heat (via lattice vibrations called phonons) rather than into usable electrical energy.

Charge Solar carrier separation

There are two main modes for charge carrier separation in a solar cell:

drift of carriers, driven by an electrostatic field established across the device diffusion of carriers from zones of high carrier concentration to zones of low carrier concentration (following a gradient of electrochemical potential).

In the widely used p-n junction solar cells, the dominant mode of charge carrier separation is by drift. However, in non-p-n-junction solar cells (typical of the third generation of solar cell research such as dye and polymer thin-film solar cells), a general electrostatic field has been confirmed to be absent, and the dominant mode of separation is via charge carrier diffusion.

The Solar p-n junction

The most commonly known solar cell is configured as a large-area p-n junction made from silicon. As a simplification, one can imagine bringing a layer of n-type silicon into direct contact with a layer of p-type silicon. In practice, p-n junctions of silicon solar cells are not made in this way, but rather, by diffusing an n-type dopant into one side of a p-type wafer (or vice versa).

If a piece of p-type silicon is placed in intimate contact with a piece of n-type silicon, then a diffusion of electrons occurs from the region of high electron concentration (the n-type side of the junction) into the region of low electron concentration (p-type side of the junction). When the electrons diffuse across the p-n junction, they recombine with holes on the p-type side. The diffusion of carriers does not happen indefinitely however, because of an electric field which is created by the imbalance of charge immediately on either side of the junction which this diffusion creates. The electric field established across the p-n junction creates a diode that promotes current to flow in only one direction across the junction. Electrons may pass from the n-type side into the p-type side, and holes may pass from the p-type side to the n-type side, but not the other way around. This region where electrons have diffused across the junction is called the depletion region because it no longer contains any mobile charge carriers. It is also known as the "space charge region".

Solar Connection to an external load

Ohmic metal-semiconductor contacts are made to both the n-type and p-type sides of the solar cell, and the electrodes connected to an external load. Electrons that are created on the n-type side, or have been "collected" by the junction and swept onto the n-type side, may travel through the wire, power the load, and continue through the wire until they reach the p-type semiconductor-metal contact. Here, they recombine with a hole that was either created as an electron-hole pair on the p-type side of the solar cell, or are swept across the junction from the n-type side after being created there.

Solar Equivalent circuit of a solar cell

The equivalent circuit of a solar cell

The schematic symbol of a solar cellTo understand the electronic behavior of a solar cell, it is useful to create a model which is electrically equivalent, and is based on discrete electrical components whose behavior is well known. An ideal solar cell may be modelled by a current source in parallel with a diode; in practice no solar cell is ideal, so a shunt resistance and a series resistance component are added to the model. The resulting equivalent circuit of a solar cell is shown on the left. Also shown, on the right, is the schematic representation of a solar cell for use in circuit diagrams.

Characteristic Solar equation

From the equivalent circuit it is evident that the current produced by the solar cell is equal to that produced by the current source, minus that which flows through the diode, minus that which flows through the shunt resistor:

I = IL - ID - ISH

where

I = output current (amperes)

IL = photogenerated current (amperes)

ID = diode current (amperes)

ISH = shunt current (amperes)

The current flowing through these elements governed by the voltage across them:

Vj = V + IRS

where

V = voltage across the output terminals (volts)

I = output current (amperes)

RS = series resistance (O)

By the Shockley diode equation, the current diverted through the diode is:

where

I0 = reverse saturation current (amperes)

n = diode ideality factor (1 for an ideal diode)

q = elementary charge

k = Boltzmann's constant

T = absolute temperature

For silicon at 25°C, volts.

By Ohm's law, the current diverted through the shunt resistor is:

where

RSH = shunt resistance (O)

Substituting these into the first equation produces the characteristic equation of a solar cell, which relates solar cell parameters to the output current and voltage:

An alternative derivation produces an equation similar in appearance, but with V on the left-hand side. The two alternatives are identities; that is, they yield precisely the same results.

In principle, given a particular operating voltage V the equation may be solved to determine the operating current I at that voltage. However, because the equation involves I on both sides in a transcendental function the equation has no general analytical solution. However, even without a solution it is physically instructive. Furthermore, it is easily solved using numerical methods. (A general analytical solution to the equation is possible using Lambert's W function, but since Lambert's W generally itself must be solved numerically this is a technicality.)

Since the parameters I0, n, RS, and RSH cannot be measured directly, the most common application of the characteristic equation is nonlinear regression to extract the values of these parameters on the basis of their combined effect on solar cell behavior.

Effect of Solar physical size

The values of I0, RS, and RSH are dependent upon the physical size of the solar cell. In comparing otherwise identical cells, a cell with twice the surface area of another will, in principle, have double the I0 because it has twice the junction area across which current can leak. It will also have half the RS and RSH because it has twice the cross-sectional area through which current can flow. For this reason, the characteristic equation is frequently written in terms of current density, or current produced per unit cell area:

where

J = current density (amperes/cm2)

JL = reverse saturation current density (amperes/cm2)

rS = specific series resistance (O-cm2)

rSH = specific shunt resistance (O-cm2)

This formulation has several advantages. One is that since cell characteristics are referenced to a common cross-sectional area they may be compared for cells of different physical dimensions. While this is of limited benefit in a manufacturing setting, where all cells tend to be the same size, it is useful in research and in comparing cells between manufacturers. Another advantage is that the density equation naturally scales the parameter values to similar orders of magnitude, which can make numerical extraction of them simpler and more accurate even with naive solution methods.

A practical limitation of this formulation is that as cell sizes shrink, certain parasitic effects grow in importance and can affect the extracted parameter values. For example, recombination and contamination of the junction tend to be greatest at the perimeter of the cell, so very small cells may exhibit higher values of J0 or lower values of rSH than larger cells that are otherwise identical. In such cases, comparisons between cells must be made cautiously and with these effects in mind.

Solar Cell temperature

Effect of temperature on the current-voltage characteristics of a solar cellTemperature affects the characteristic equation in two ways: directly, via T in the exponential term, and indirectly via its effect on I0. (Strictly speaking, temperature affects all of the terms, but these two far more significantly than the others.) While increasing T reduces the magnitude of the exponent in the characteristic equation, the value of I0 increases in proportion to expT. The net effect is to reduce VOC linearly with increasing temperature. The magnitude of this reduction is inversely proportional to VOC; that is, cells with higher values of VOC suffer smaller reductions in voltage with increasing temperature. For most crystalline silicon solar cells the reduction is about 0.50%/°C, though the rate for the highest-efficiency crystalline silicon cells is around 0.35%/°C. By way of comparison, the rate for amorphous silicon solar cells is 0.20-0.30%/°C, depending on how the cell is made.

The amount of photogenerated current IL increases slightly with increasing temperature because of an increase in the number of thermally generated carriers in the cell. This effect is slight, however: about 0.065%/°C for crystalline silicon cells and 0.09% for amorphous silicon cells.

The overall effect of temperature on cell efficiency can be computed using these factors in combination with the characteristic equation. However, since the change in voltage is much stronger than the change in current, the overall effect on efficiency tends to be similar to that on voltage. Most crystalline silicon solar cells decline in efficiency by 0.50%/°C and most amorphous cells decline by 0.15-0.25%/°C. The figure to the right shows I-V curves that might typically be seen for a crystalline silicon solar cell at various temperatures.

Solar Series resistance

Effect of series resistance on the current-voltage characteristics of a solar cellAs series resistance increases, the voltage drop between the junction voltage and the terminal voltage becomes greater for the same flow of current. The result is that the current-controlled portion of the I-V curve begins to sag toward the origin, producing a significant decrease in the terminal voltage V and a slight reduction in ISC. Very high values of RS will also produce a significant reduction in ISC; in these regimes, series resistance dominates and the behavior of the solar cell resembles that of a resistor. These effects are shown for crystalline silicon solar cells in the I-V curves displayed in the figure to the right.

Solar Shunt resistance

Effect of shunt resistance on the current-voltage characteristics of a solar cellAs shunt resistance decreases, the flow of current diverted through the shunt resistor increases for a given level of junction voltage. The result is that the voltage-controlled portion of the I-V curve begins to sag toward the origin, producing a significant decrease in the terminal current I and a slight reduction in VOC. Very low values of RSH will produce a significant reduction in VOC. Much as in the case of a high series resistance, a badly shunted solar cell will take on operating characteristics similar to those of a resistor. These effects are shown for crystalline silicon solar cells in the I-V curves displayed in the figure to the right.

Solar Reverse saturation current

Effect of reverse saturation current on the current-voltage characteristics of a solar cellIf one assumes infinite shunt resistance, the characteristic equation can be solved for VOC:

Thus, an increase in I0 produces a reduction in VOC proportional to the inverse of the logarithm of the increase. This explains mathematically the reason for the reduction in VOC that accompanies increases in temperature described above. The effect of reverse saturation current on the I-V curve of a crystalline silicon solar cell are shown in the figure to the right. Physically, reverse saturation current is a measure of the "leakage" of carriers across the p-n junction in reverse bias. This leakage is a result of carrier recombination in the neutral regions on either side of the junction.

Solar Ideality factor

Effect of ideality factor on the current-voltage characteristics of a solar cellThe ideality factor (also called the emissivity factor) is a fitting parameter that describes how closely the diode's behavior matches that predicted by theory, which assumes the p-n junction of the diode is an infinite plane and no recombination occurs within the space-charge region. A perfect match to theory is indicated when n = 1. When recombination in the space-charge region dominate other recombination, however, n = 2. The effect of changing ideality factor independently of all other parameters is shown for a crystalline silicon solar cell in the I-V curves displayed in the figure to the right.

Most solar cells, which are quite large compared to conventional diodes, well approximate an infinite plane and will usually exhibit near-ideal behavior under standard test conditions (). Under certain operating conditions, however, device operation may be dominated by recombination in the space-charge region. This is characterized by a significant increase in I0 as well as an increase in ideality factor to . The former tends to erode solar cell output voltage while the former acts to increase it. The net effect, therefore, is a combination of the increase in voltage shown for increasing n in the figure to the right and the decrease in voltage shown for increasing I0 in the figure above. Typically, I0 is the more significant factor and the result is a reduction in voltage.

Solar cell efficiency factors

Energy Solar conversion efficiency

A solar cell's energy conversion efficiency (?, "eta"), is the percentage of power converted (from absorbed light to electrical energy) and collected, when a solar cell is connected to an electrical circuit. This term is calculated using the ratio of the maximum power point, Pm, divided by the input light irradiance (E, in W/m²) under standard test conditions (STC) and the surface area of the solar cell (Ac in m²).

STC specifies a temperature of 25°C and an irradiance of 1000 W/m² with an air mass 1.5 (AM1.5) spectrum. These correspond to the irradiance and spectrum of sunlight incident on a clear day upon a sun-facing 37°-tilted surface with the sun at an angle of 41.81° above the horizon. This condition approximately represents solar noon near the spring and autumn equinoxes in the continental United States with surface of the cell aimed directly at the sun. Thus, under these conditions a solar cell of 12% efficiency with a 100 cm2 (0.01 m2) surface area can be expected to produce approximately 1.2 watts of power.

The losses of a solar cell may be broken down into reflectance losses, thermodynamic efficiency, recombination losses and resistive electrical loss. The overall efficiency is the product of each of these individual losses.

Due to the difficulty in measuring these parameters directly, other parameters are measured instead: Thermodynamic Efficiency, Quantum Efficiency, VOC ratio, and Fill Factor. Reflectance losses are a portion of the Quantum Efficiency under "External Quantum Efficiency". Recombination losses make up a portion of the Quantum Efficiency, VOC ratio, and Fill Factor. Resistive losses are predominantly categorized under Fill Factor, but also make up minor portions of the Quantum Efficiency, VOC ratio.

Thermodynamic Solar Efficiency Limit

Solar cells operate as quantum energy conversion devices, and are therefore subject to the "Thermodynamic Efficiency Limit". Photons with an energy below the band gap of the absorber material cannot generate a hole-electron pair, and so their energy is not converted to useful output and only generates heat if absorbed. For photons with an energy above the band gap energy, only a fraction of the energy above the band gap can be converted to useful output. When a photon of greater energy is absorbed, the excess energy above the band gap is converted to kinetic energy of the carrier combination. The excess kinetic energy is converted to heat through phonon interactions as the kinetic energy of the carriers slows to equilibrium velocity.

Solar cells with multiple band gap absorber materials are able to more efficiently convert the solar spectrum. By using multiple band gaps, the solar spectrum may be broken down into smaller bins where the thermodynamic efficiency limit is higher for each bin.

Quantum Solar efficiency

As described above, when a photon is absorbed by a solar cell it is converted to an electron-hole pair. This electron-hole pair may then travel to the surface of the solar cell and contribute to the current produced by the cell; such a carrier is said to be collected. Alternatively, the carrier may give up its energy and once again become bound to an atom within the solar cell without reaching the surface; this is called recombination, and carriers that recombine do not contribute to the production of electrical current.

Quantum efficiency refers to the percentage of photons that are converted to electric current (i.e., collected carriers) when the cell is operated under short circuit conditions. External quantum efficiency is the fraction of incident photons that are converted to electrical current, while internal quantum efficiency is the fraction of absorbed photons that are converted to electrical current. Mathematically, internal quantum efficiency is related to external quantum efficiency by the reflectance of the solar cell; given a perfect anti-reflection coating, they are the same.

Quantum efficiency should not be confused with energy conversion efficiency, as it does not convey information about the power collected from the solar cell. Furthermore, quantum efficiency is most usefully expressed as a spectral measurement (that is, as a function of photon wavelength or energy). Since some wavelengths are absorbed more effectively than others in most semiconductors, spectral measurements of quantum efficiency can yield information about which parts of a particular solar cell design are most in need of improvement.

Maximum-power Solar point

A solar cell may operate over a wide range of voltages (V) and currents (I). By increasing the resistive load on an irradiated cell continuously from zero (a short circuit) to a very high value (an open circuit) one can determine the maximum-power point, the point that maximizes V×I; that is, the load for which the cell can deliver maximum electrical power at that level of irradiation. (The output power is zero in both the short circuit and open circuit extremes). A high quality, monocrystalline silicon solar cell, at 25 °C cell temperature, may produce 0.60 volts open-circuit (Voc). The cell temperature in full sunlight, even with 25 °C air temperature, will probably be close to 45 °C, reducing the open-circuit voltage to 0.55 volts per cell. The voltage drops modestly, with this type of cell, until the short-circuit current is approached (Isc). Maximum power (with 45 °C cell temperature) is typically produced with 75% to 80% of the open-circuit voltage (0.43 volts in this case) and 90% of the short-circuit current. This output can be up to 70% of the Voc x Isc product. The short-circuit current (Isc) from a cell is nearly proportional to the illumination, while the open-circuit voltage (Voc) may drop only 10% with a 80% drop in illumination. Lower-quality cells have a more rapid drop in voltage with increasing current and could produce only 1/2 Voc at 1/2 Isc. The usable power output could thus drop from 70% of the Voc x Isc product to 50% or even as little as 25%. Vendors who rate their solar cell "power" only as Voc x Isc, without giving load curves, can be seriously distorting their actual performance.

The maximum power point of a photovoltaic varies with incident illumination. For systems large enough to justify the extra expense, a maximum power point tracker tracks the instantaneous power by continually measuring the voltage and current (and hence, power transfer), and uses this information to dynamically adjust the load so the maximum power is always transferred, regardless of the variation in lighting.

Solar Fill factor

Another defining term in the overall behavior of a solar cell is the fill factor (FF). This is the ratio of the maximum power point divided by the open circuit voltage (Voc) and the short circuit current (Isc):

Comparison of Solar energy conversion efficiencies

At this point, discussion of the different ways to calculate efficiency for space cells and terrestrial cells is necessary to alleviate confusion. In space, where there is no atmosphere, the spectrum of the sun is relatively unfiltered. However on earth, with air filtering the incoming light, the solar spectrum changes. To account for the spectral differences, a system was devised to calculate this filtering effect. Simply, the filtering effect ranges from Air Mass 0 (AM0) in space, to approximately Air Mass 1.5 on earth. Multiplying the spectral differences by the quantum efficiency of the solar cell in question will yield the efficiency of the device. For example, a Silicon solar cell in space might have an efficiency of 14% at AM0, but have an efficiency of 16% on earth at AM 1.5. Terrestrial efficiencies typically are greater than space efficiencies.

Solar cell efficiencies vary from 6% for amorphous silicon-based solar cells to 40.7% with multiple-junction research lab cells and 42.8% with multiple dies assembled into a hybrid package. Solar cell energy conversion efficiencies for commercially available multicrystalline Si solar cells are around 14-19%. The highest efficiency cells have not always been the most economical for example a 30% efficient multijunction cell based on exotic materials such as gallium arsenide or indium selenide and produced in low volume might well cost one hundred times as much as an 8% efficient amorphous silicon cell in mass production, while only delivering about four times the electrical power.

However, there is a way to "boost" solar power. By increasing the light intensity, typically photogenerated carriers are increased, resulting in increased efficiency by up to 15%. These so-called "concentrator systems" have only begun to become cost-competitive as a result of the development of high efficiency GaAs cells. The increase in intensity is typically accomplished by using concentrating optics. A typical concentrator system may use a light intensity 6-400 times the sun, and increase the efficiency of a one sun GaAs cell from 31% at AM 1.5 to 35%.

A common method used to express economic costs of electricity-generating systems is to calculate a price per delivered kilowatt-hour (kWh). The solar cell efficiency in combination with the available irradiation has a major influence on the costs, but generally speaking the overall system efficiency is important. Using the commercially available solar cells (as of 2006) and system technology leads to system efficiencies between 5 and 19%. As of 2005, photovoltaic electricity generation costs ranged from ~0.60 US$/kWh (0.50/kWh) (central Europe) down to ~0.30 US$/kWh (0.25/kWh) in regions of high solar irradiation. This electricity is generally fed into the electrical grid on the customer's side of the meter. The cost can be compared to prevailing retail electric pricing (as of 2005), which varied from between 0.04 and 0.50 US$/kWh worldwide. (Note: in addition to solar irradiance profiles, these costs/kwh calculations will vary depending on assumptions for years of useful life of a system. Most c-Si panels are warrantied for 25 years and should see 35+ years of useful life.)

The chart at the right illustrates the various commercial large-area module energy conversion efficiencies and the best laboratory efficiencies obtained for various materials and technologies.

Reported timeline of solar cell energy conversion efficiencies (from National Renewable Energy Laboratory (USA)

Solar Watts peak

Since solar cell output power depends on multiple factors, such as the sun's incidence angle, for comparison purposes between different cells and panels, the measure of watts peak (Wp) is used. It is the output power under these conditions known as STC:

insolation (solar irradiance) 1000 W/m²

solar reference spectrum AM (airmass) 1.5

cell temperature 25°C

Solar cells and energy payback

Energy payback is the recovery (period) of the energy spent for manufacturing of the respective technical energy systems, also called harvesting ratio (ISO 13602).

In the 1990s, when silicon cells were twice as thick, efficiencies were 30% lower than today and lifetimes were shorter, it may well have cost more energy to make a cell than it could generate in a lifetime. In the meantime, the technology has progressed significantly, and the energy payback time of a modern photovoltaic module is typically from 1 to 4 years depending on the type and where it is used (see net energy gain). With a typical lifetime of 20 to 30 years, this means that modern solar cells are net energy producers, i.e they generate much more energy over their lifetime than the energy expended in producing them.

Solar Light-absorbing materials

All solar cells require a light absorbing material contained within the cell structure to absorb photons and generate electrons via the photovoltaic effect. The materials used in solar cells tend to have the property of preferentially absorbing the wavelengths of solar light that reach the earth surface; however, some solar cells are optimized for light absorption beyond Earth's atmosphere as well. Light absorbing materials can often be used in multiple physical configurations to take advantage of different light absorption and charge separation mechanisms. Many currently available solar cells are configured as bulk materials that are subsequently cut into wafers and treated in a "top-down" method of synthesis (silicon being the most prevalent bulk material). Other materials are configured as thin-films (inorganic layers, organic dyes, and organic polymers) that are deposited on supporting substrates, while a third group are configured as nanocrystals and used as quantum dots (electron-confined nanoparticles) embedded in a supporting matrix in a "bottom-up" approach. Silicon remains the only material that is well-researched in both bulk and thin-film configurations.

There are many new alternatives to Silicon photocells. Proprietary nano-particle silicon printing processes promises many of the photovoltaic features that conventional silicon can never achieve. It can be printed reel to reel on stainless steel or other high temperature substrates.

However, most of the work on the next generation of photovoltaics is directed at printing onto low cost flexible polymer film and ultimately on common packaging materials. The main contenders are currently CIGS, CdTe, DSSC and organic photovoltaics.

The following is a current list of light absorbing materials, listed by configuration and substance-name:

Solar Bulk

These bulk technologies are often referred to as wafer-based manufacturing. In other words, in each of these approaches, self-supporting wafers between 180 to 240 micrometers thick are processed and then soldered together to form a solar cell module. A general description of silicon wafer processing is provided in Manufacture and Devices.

Solar Silicon

Basic structure of a silicon based solar cell and its working mechanism.By far, the most prevalent bulk material for solar cells is crystalline silicon (abbreviated as a group as c-Si), also known as "solar grade silicon". Bulk silicon is separated into multiple categories according to crystallinity and crystal size in the resulting ingot, ribbon, or wafer.

monocrystalline silicon (c-Si): often made using the Czochralski process. Single-crystal wafer cells tend to be expensive, and because they are cut from cylindrical ingots, do not completely cover a square solar cell module without a substantial waste of refined silicon. Hence most c-Si panels have uncovered gaps at the four corners of the cells. Poly- or multicrystalline silicon (poly-Si or mc-Si): made from cast square ingots large blocks of molten silicon carefully cooled and solidified. These cells are less expensive to produce than single crystal cells but are less efficient.

Ribbon silicon: formed by drawing flat thin films from molten silicon and having a multicrystalline structure. These cells have lower efficiencies than poly-Si, but save on production costs due to a great reduction in silicon waste, as this approach does not require sawing from ingots. Silicon solar cells are wide area silicon.

Solar Thin films

The various thin-film technologies currently being developed reduce the amount (or mass) of light absorbing material required in creating a solar cell. This can lead to reduced processing costs from that of bulk materials (in the case of silicon thin films) but also tends to reduce energy conversion efficiency, although many multi-layer thin films have efficiencies above those of bulk silicon wafers.

Cadmium telluride solar cell

A cadmium telluride solar cell is a solar cell based on cadmium telluride, an efficient light-absorbing material for thin-film cells. Compared to other thin-film materials, CdTe is easier to deposit and more suitable for large-scale production.

Despite much discussion of the toxicity of CdTe-based solar cells, this is the only technology (apart from amorphous silicon) that can be delivered on a large scale. The perception of the toxicity of CdTe is based on the toxicity of elemental cadmium, a heavy metal that is a cumulative poison. However it has been shown that the release of cadmium to the atmosphere is lower with CdTe-based solar cells than with silicon photovoltaics and other thin-film solar cell technologies.

Solar Copper-Indium Selenide

Possible combinations of I III VI elements in the periodic table that have photovoltaic effect

The materials based on CuInSe2 that are of interest for photovoltaic applications include several elements from groups I, III and VI in the periodic table. These semiconductors are especially attractive for thin film solar cell application because of their high optical absorption coefficients and versatile optical and electrical characteristics which can in principle be manipulated and tuned for a specific need in a given device. CIS is an abbreviation for general chalcopyrite films of copper indium selenide (CuInSe2), CIGS mentioned below is a variation of CIS. CIS films (no Ga) achieved greater than 14% efficiency. However, manufacturing costs of CIS solar cells at present are high when compared with amorphous silicon solar cells but continuing work is leading to more cost-effective production processes. The first large-scale production of CIS modules was started in 2006 in Germany by Wuerth Solar.

When gallium is substituted for some of the indium in CIS, the material is sometimes called CIGS , or copper indium/gallium diselenide, a solid mixture of the semiconductors CuInSe2 and CuGaSe2, often abbreviated by the chemical formula CuInxGa(1-x)Se2. Unlike the conventional silicon based solar cell, which can be modelled as a simple p-n junction (see under semiconductor), these cells are best described by a more complex heterojunction model. The best efficiency of a thin-film solar cell as of March 2008 was 19.9% with CIGS absorber layer. Higher efficiencies (around 30%) can be obtained by using optics to concentrate the incident light. The use of gallium increases the optical bandgap of the CIGS layer as compared to pure CIS, thus increasing the open-circuit voltage. In another point of view, gallium is added to replace as much indium as possible due to gallium's relative availability to indium. Approximately 70% of indium currently produced is used by the flat-screen monitor industry. Some investors in solar technology worry that production of CIGS cells will be limited by the availability of indium. Producing 2 GW of CIGS cells (roughly the amount of silicon cells produced in 2006) would use about 10% of the indium produced in 2004. For comparison, silicon solar cells used up 33% of the world's electronic grade silicon production in 2006. Nanosolar claims to waste only 5% of the indium it uses. As of 2006, the best conversion efficiency for flexible CIGS cells on polyimide is 14.1% by Tiwari et al, at the ETH, Switzerland.

That being said, indium can easily be recycled from decommissioned PV modules. The recycling program in Germany is an example that highlights the regenerative industrial paradigm: "From cradle to cradle".

Selenium allows for better uniformity across the layer and so the number of recombination sites in the film are reduced which benefits the quantum efficiency and thus the conversion efficiency.

Gallium arsenide (GaAs) Solar multijunction

High-efficiency multijunction cells were originally developed for special applications such as satellites and space exploration, but at present, their use in terrestrial concentrators might be the lowest cost alternative in terms of $/kWh and $/W. These multijunction cells consist of multiple thin films produced using Metalorganic vapour phase epitaxy. A triple-junction cell, for example, may consist of the semiconductors: GaAs, Ge, and GaInP2. Each type of semiconductor will have a characteristic band gap energy which, loosely speaking, causes it to absorb light most efficiently at a certain color, or more precisely, to absorb electromagnetic radiation over a portion of the spectrum. The semiconductors are carefully chosen to absorb nearly all of the solar spectrum, thus generating electricity from as much of the solar energy as possible.

GaAs based multijunction devices are the most efficient solar cells to date, reaching a record high of 40.7% efficiency under solar concentration and laboratory conditions.

This technology is currently being utilized in the Mars rover missions.

Tandem solar cells based on monolithic, series connected, gallium indium phosphide (GaInP), gallium arsenide GaAs, and germanium Ge pn junctions, are seeing demand rapidly rise. In just the past 12 months (12/2006 - 12/2007), the cost of 4N gallium metal has risen from about $350 per kg to $680 per kg. Additionally, germanium metal prices have risen substantially to $1000-$1200 per kg this year. Those materials include gallium (4N, 6N and 7N Ga), arsenic (4N, 6N and 7N) and germanium, pyrolitic boron nitride (pBN) crucibles for growing crystals, and boron oxide, these products are critical to the entire substrate manufacturing industry.

Triple-junction GaAs solar cells were also being used as the power source of the Dutch four-time World Solar Challenge winners Nuna in 2005 and 2007, and also by the Dutch solar cars Solutra (2005) and Twente One (2007).

The Dutch Radboud University Nijmegen set the record for thin film solar cell effiency using a single junction GaAs to 25.8% in august 2008 using only 4 µm thick GaAs layer which can be transferred from a wafer base to glas or plastic film.

Solar Light-absorbing dyes (DSSC)

Typically a ruthenium metalorganic dye (Ru-centered) is used as a monolayer of light-absorbing material. The dye-sensitized solar cell depends on a mesoporous layer of nanoparticulate titanium dioxide to greatly amplify the surface area (200-300 m²/g TiO2, as compared to approximately 10 m²/g of flat single crystal). The photogenerated electrons from the light absorbing dye are passed on to the n-type TiO2, and the holes are passed to an electrolyte on the other side of the dye. The circuit is completed by a redox couple in the electrolyte, which can be liquid or solid. This type of cell allows a more flexible use of materials, and is typically manufactured by screen printing, with the potential for lower processing costs than those used for bulk solar cells. However, the dyes in these cells also suffer from degradation under heat and UV light, and the cell casing is difficult to seal due to the solvents used in assembly. In spite of the above, this is a popular emerging technology with some commercial impact forecast within this decade.

Organic/polymer solar cells

Organic solar cells and Polymer solar cells are built from thin films (typically 100 nm) of organic semiconductors such as polymers and small-molecule compounds like polyphenylene vinylene, copper phthalocyanine (a blue or green organic pigment) and carbon fullerenes. Energy conversion efficiencies achieved to date using conductive polymers are low compared to inorganic materials, with the highest reported efficiency of 6.5% for a tandem cell architecture. However, these cells could be beneficial for some applications where mechanical flexibility and disposability are important.

These devices differ from inorganic semiconductor solar cells in that they do not rely on the large built in electric field of a PN junction to separate the electrons and holes created when photons are absorbed. The active region of an organic device consists of two materials, one which acts as an electron donor and the other as an acceptor. When a photon is converted into an electron hole pair, typically in the donor material, the charges tend to remain bound in the form of an exciton, and are separated when the exciton diffuses to the donor-acceptor interface. The short exciton diffusion lengths of most polymer systems tend to limit the efficiency of such devices. Nanostructured interfaces, sometimes in the form of bulk heterojunctions, can improve performance.

Silicon Thin Solar Films

Silicon thin-films are mainly deposited by chemical vapor deposition (typically plasma-enhanced (PE-CVD)) from silane gas and hydrogen gas. Depending on the deposition's parameters, this can yield:

Amorphous silicon (a-Si or a-Si:H) Protocrystalline silicon]] or Nanocrystalline silicon (nc-Si or nc-Si:H), also called microcrystalline silicon. These types of silicon present dangling and twisted bonds, which results in deep defects (energy levels in the bandgap) as well as deformation of the valence and conduction bands (band tails). The solar cells made from these materials tend to have lower energy conversion efficiency than bulk silicon, but are also less expensive to produce. The quantum efficiency of thin film solar cells is also lower due to reduced number of collected charge carriers per incident photon.

Amorphous silicon has a higher bandgap (1.7 eV) than crystalline silicon (c-Si) (1.1 eV), which means it absorbs the visible part of the solar spectrum more strongly than the infrared portion of the spectrum. As nc-Si has about the same bandgap as c-Si, the two materials can be combined in thin layers, creating a layered cell called a tandem cell. The top cell in a-Si absorbs the visible light and leaves the infrared part of the spectrum for the bottom cell in nanocrystalline Si.

Recently, solutions to overcome the limitations of thin-film crystalline silicon have been developed. Light trapping schemes where the incoming light is obliquely coupled into the silicon and the light traverses the film several times enhance the absorption of sunlight in the films. Thermal processing techniques enhance the crystallinity of the silicon and pacify electronic defects.

A silicon thin film technology is being developed for building integrated photovoltaics (BIPV) in the form of semi-transparent solar cells which can be applied as window glazing. These cells function as window tinting while generating electricity.

Nanocrystalline solar cells

These structures make use of some of the same thin-film light absorbing materials but are overlain as an extremely thin absorber on a supporting matrix of conductive polymer or mesoporous metal oxide having a very high surface area to increase internal reflections (and hence increase the probability of light absorption). Using nanocrystals allows one to design architectures on the length scale of nanometers, the typical exciton diffusion length. In particular, single-nanocrystal ('channel') devices, an array of single p-n junctions between the electrodes and separated by a period of about a diffusion length, represent a new architecture for solar cells and potentially high efficiency.

Solar Concentrating photovoltaics (CPV)

Concentrating photovoltaic systems use a large area of lenses or mirrors to focus sunlight on a small area of photovoltaic cells. If these systems use single or dual-axis tracking to improve performance, they may be referred to as Heliostat Concentrator Photovoltaics (HCPV). The primary attraction of CPV systems is their reduced usage of semiconducting material which is expensive and currently in short supply. Additionally, increasing the concentration ratio improves the performance of general photovoltaic materials. Despite the advantages of CPV technologies their application has been limited by the costs of focusing, tracking and cooling equipment. On October 25, 2006, the Australian federal government and the Victorian state government together with photovoltaic technology company Solar Systems announced a project using this technology, Solar power station in Victoria, planned to come online in 2008 and be completed by 2013. This plant, at 154 MW, would be ten times larger than the largest current photovoltaic plant in the world.

Silicon solar cell device manufacture

Solar powered scientific calculatorBecause solar cells are semiconductor devices, they share many of the same processing and manufacturing techniques as other semiconductor devices such as computer and memory chips. However, the stringent requirements for cleanliness and quality control of semiconductor fabrication are a little more relaxed for solar cells. Most large-scale commercial solar cell factories today make screen printed poly-crystalline silicon solar cells. Single crystalline wafers which are used in the semiconductor industry can be made into excellent high efficiency solar cells, but they are generally considered to be too expensive for large-scale mass production.

Poly-crystalline silicon wafers are made by wire-sawing block-cast silicon ingots into very thin (180 to 350 micrometer) slices or wafers. The wafers are usually lightly p-type doped. To make a solar cell from the wafer, a surface diffusion of n-type dopants is performed on the front side of the wafer. This forms a p-n junction a few hundred nanometers below the surface.

Antireflection coatings, which increase the amount of light coupled into the solar cell, are typically next applied. Over the past decade, silicon nitride has gradually replaced titanium dioxide as the antireflection coating of choice because of its excellent surface passivation qualities (i.e., it prevents carrier recombination at the surface of the solar cell). It is typically applied in a layer several hundred nanometers thick using plasma-enhanced chemical vapor deposition (PECVD). Some solar cells have textured front surfaces that, like antireflection coatings, serve to increase the amount of light coupled into the cell. Such surfaces can usually only be formed on single-crystal silicon, though in recent years methods of forming them on multicrystalline silicon have been developed.

The wafer then has a full area metal contact made on the back surface, and a grid-like metal contact made up of fine "fingers" and larger "busbars" are screen-printed onto the front surface using a silver paste. The rear contact is also formed by screen-printing a metal paste, typically aluminium. Usually this contact covers the entire rear side of the cell, though in some cell designs it is printed in a grid pattern. The paste is then fired at several hundred degrees Celsius to form metal electrodes in ohmic contact with the silicon. After the metal contacts are made, the solar cells are interconnected in series (and/or parallel) by flat wires or metal ribbons, and assembled into modules or "solar panels". Solar panels have a sheet of tempered glass on the front, and a polymer encapsulation on the back. Tempered glass cannot be used with amorphous silicon cells because of the high temperatures during the deposition process.

Solar Lifespan

Most commercially available solar cells are capable of producing electricity for at least twenty years without a significant decrease in efficiency.

Solar Costs

Solar Slicing costs

University of Utah engineers devised a new way to slice thin wafers of the chemical element germanium for use in the most efficient type of solar power cells. The new method should lower the cost of such cells by reducing the waste and breakage of the brittle semiconductor.

Low Cost Solar Cell

Dye-sensitized solar cell is considered the low cost solar cell.

This cell is extremely promising because it is made of low-cost materials and does not need elaborate apparatus to manufacture, so it can be made in a DIY way allowing more players to produce it than any other type of solar cell. In bulk it should be significantly less expensive than older solid-state cell designs. It can be engineered into flexible sheets. Although its conversion efficiency is less than the best thin film cells, its price/performance ratio should be high enough to allow them to compete with fossil fuel electrical generation.

Current research on Solar materials and devices

There are currently many research groups active in the field of photovoltaics in universities and research institutions around the world. This research can be divided into three areas: making current technology solar cells cheaper and/or more efficient to effectively compete with other energy sources; developing new technologies based on new solar cell architectural designs; and developing new materials to serve as light absorbers and charge carriers.

Silicon Solar processing

One way of reducing the cost is to develop cheaper methods of obtaining silicon that is sufficiently pure. Silicon is a very common element, but is normally bound in silica, or silica sand. Processing silica (SiO2) to produce silicon is a very high energy process - at current efficiencies, it takes over two years for a conventional solar cell to generate as much energy as was used to make the silicon it contains. More energy efficient methods of synthesis are not only beneficial to the solar industry, but also to industries surrounding silicon technology as a whole.

The current industrial production of silicon is via the reaction between carbon (charcoal) and silica at a temperature around 1700 degrees Celsius. In this process, known as carbothermic reduction, each tonne of silicon (metallurgical grade, about 98% pure) is produced with the emission of about 1.5 tonnes of carbon dioxide.

Solid silica can be directly converted (reduced) to pure silicon by electrolysis in a molten salt bath at a fairly mild temperature (800 to 900 degrees Celsius). While this new process is in principle the same as the FFC Cambridge Process which was first discovered in late 1996, the interesting laboratory finding is that such electrolytic silicon is in the form of porous silicon which turns readily into a fine powder, (with a particle size of a few micrometres), and may therefore offer new opportunities for development of solar cell technologies.

Another approach is also to reduce the amount of silicon used and thus cost, is by micromachining wafers into very thin, virtually transparent layers that could be used as transparent architectural coverings. The technique involves taking a silicon wafer, typically 1 to 2 mm thick, and making a multitude of parallel, transverse slices across the wafer, creating a large number of slivers that have a thickness of 50 micrometres and a width equal to the thickness of the original wafer. These slices are rotated 90 degrees, so that the surfaces corresponding to the faces of the original wafer become the edges of the slivers. The result is to convert, for example, a 150 mm diameter, 2 mm-thick wafer having an exposed silicon surface area of about 175 cm² per side into about 1000 slivers having dimensions of 100 mm x 2 mm x 0.1 mm, yielding a total exposed silicon surface area of about 2000 cm² per side. As a result of this rotation, the electrical doping and contacts that were on the face of the wafer are located the edges of the sliver, rather than the front and rear as is the case with conventional wafer cells. This has the interesting effect of making the cell sensitive from both the front and rear of the cell (a property known as bifaciality). Using this technique, one silicon wafer is enough to build a 140 watt panel, compared to about 60 wafers needed for conventional modules of same power output.

Thin-film Solar processing

Thin-film solar cells use less than 1% of the raw material (silicon or other light absorbers) compared to wafer based solar cells, leading to a significant price drop per kWh. There are many research groups around the world actively researching different thin-film approaches and/or materials, however it remains to be seen vague if these solutions can generate the same space-efficiency as traditional silicon processing.

One particularly promising technology is crystalline silicon thin films on glass substrates. This technology makes use of the advantages of crystalline silicon as a solar cell material, with the cost savings of using a thin-film approach.

Another interesting aspect of thin-film solar cells is the possibility to deposit the cells on all kind of materials, including flexible substrates (PET for example), which opens a new dimension for new applications.

Metamorphic Multijunction Solar Cell

The National Renewable Energy Laboratory won a R&D Magazine's R&D 100 Awards for its Metamorphic Multijunction Solar Cell, an ultra-light and flexible cell that converts solar energy with record efficiency .

The ultra-light, highly efficient solar cell was developed at NREL and is being commercialized by Emcore Corp. of Albuquerque, N.M., in partnership with the Air Force Research Laboratories Space Vehicles Directorate at Kirtland Air Force Base in Albuquerque.

It represents a new class of solar cells with clear advantages in performance, engineering design, operation and cost. For decades, conventional cells have featured wafers of semiconducting materials with similar crystalline structure. Their performance and cost effectiveness is constrained by growing the cells in an upright configuration. Meanwhile, the cells are rigid, heavy and thick with a bottom layer made of germanium.

In the new method, the cell is grown upside down. These layers use high-energy materials with extremely high quality crystals, especially in the upper layers of the cell where most of the power is produced. Not all of the layers follow the lattice pattern of even atomic spacing. Instead, the cell includes a full range of atomic spacing, which allows for greater absorption and use of sunlight. The thick, rigid germanium layer is removed, reducing the cell's cost and 94% of its weight. By turning the conventional approach to cells on its head, the result is an ultra-light and flexible cell that also converts solar energy with record efficiency (40.8 percent under 326 suns concentration).

Polymer Solar processing

The invention of conductive polymers (for which Alan Heeger, Alan G. MacDiarmid and Hideki Shirakawa were awarded a Nobel prize) may lead to the development of much cheaper cells that are based on inexpensive plastics. However, all organic solar cells made to date suffer from degradation upon exposure to UV light, and hence have lifetimes which are far too short to be viable. The conjugated double bond systems in the polymers, which carry the charge, are always susceptible to breaking up when radiated with shorter wavelengths. Additionally, most conductive polymers, being highly unsaturated and reactive, are highly sensitive to atmospheric moisture and oxidation, making commercial applications difficult.

Nanoparticle Solar processing

Experimental non-silicon solar panels can be made of quantum heterostructures, eg. carbon nanotubes or quantum dots, embedded in conductive polymers or mesoporous metal oxides. In addition, thin films of many of these materials on conventional silicon solar cells can increase the optical coupling efficiency into the silicon cell, thus boosting the overall efficiency. By varying the size of the quantum dots, the cells can be tuned to absorb different wavelengths. Although the research is still in its infancy, quantum dot-modified photovoltaics may be able to achieve up to 42 percent energy conversion efficiency due to multiple exciton generation(MEG).

Researchers located at the University of California, San Diego have come up with a way of making solar photovoltaic cells more efficient by making them fuzzy with indium phosphide nanowires. It sounds similar to a project announced by a consortium of German universities, working in concert with Harvard University Science department.

Transparent Solar conductors

Many new solar cells use transparent thin films that are also conductors of electrical charge. The dominant conductive thin films used in research now are transparent conductive oxides (abbreviated "TCO"), and include fluorine-doped tin oxide (SnO2:F, or "FTO"), doped zinc oxide (e.g.: ZnO:Al), and indium tin oxide (abbreviated "ITO"). These conductive films are also used in the LCD industry for flat panel displays. The dual function of a TCO allows light to pass through a substrate window to the active light absorbing material beneath, and also serves as an ohmic contact to transport photogenerated charge carriers away from that light absorbing material. The present TCO materials are effective for research, but perhaps are not yet optimized for large-scale photovoltaic production. They require very special deposition conditions at high vacuum, they can sometimes suffer from poor mechanical strength, and most have poor transmittance in the infrared portion of the spectrum (e.g.: ITO thin films can also be used as infrared filters in airplane windows). These factors make large-scale manufacturing more costly.

A relatively new area has emerged using carbon nanotube networks as a transparent conductor for organic solar cells. Nanotube networks are flexible and can be deposited on surfaces a variety of ways. With some treatment, nanotube films can be highly transparent in the infrared, possibly enabling efficient low bandgap solar cells. Nanotube networks are p-type conductors, whereas traditional transparent conductors are exclusively n-type. The availability of a p-type transparent conductor could lead to new cell designs that simplify manufacturing and improve efficiency.

Silicon wafer based solar cells

Despite the numerous attempts at making better solar cells by using new and exotic materials, the reality is that the photovoltaics market is still dominated by silicon wafer-based solar cells (first-generation solar cells). This means that most solar cell manufacturers are equipped to produce these type of solar cells. Therefore, a large body of research is currently being done all over the world to create silicon wafer-based solar cells that can achieve higher conversion efficiency without an exorbitant increase in production cost. The aim of the research is to achieve the lowest cost per watt solar cell design that is suitable for commercial production.

IBM has a semiconductor wafer reclamation process that uses a specialized pattern removal technique to repurpose scrap semiconductor wafers to a form used to manufacture silicon-based solar panels. The new process was recently awarded the -2007 Most Valuable Pollution Prevention Award from The National Pollution Prevention Roundtable (NPPR).

Infrared solar cells

Researchers at Idaho National Laboratory, along with partners at Microcontinuum Inc. (Cambridge, MA) and Patrick Pinhero of the University of Missouri, have devised an inexpensive way to produce plastic sheets containing billions of nanoantennas that collect heat energy generated by the sun and other sources, which garnered two 2007 Nano50 awards. The technology is the first step toward a solar energy collector that could be mass-produced on flexible materials. While methods to convert the energy into usable electricity still need to be developed, the sheets could one day be manufactured as lightweight "skins" that power everything from hybrid cars to computers and iPods with higher efficiency than traditional solar cells. The nanoantennas also have the potential to act as cooling devices that draw waste heat from buildings or electronics without using electricity. The nanoantennas target mid-infrared rays, which the Earth continuously radiates as heat after absorbing energy from the sun during the day; also double-sided nanoantenna sheets can harvest energy from different parts of the sun's spectrum. In contrast, traditional solar cells can only use visible light, rendering them idle after dark.

Also Konarka is researching infrared light activated photovoltaics which would enable night-time power generation.

Solar Validation and Manufacturers

National Renewable Energy Laboratory tests and validates solar technologies.

Solar cells are manufactured primarily in Japan, China, Germany, Taiwan and the USA, though numerous other nations have or are acquiring significant solar cell production capacity. While technologies are constantly evolving toward higher efficiencies, the most effective cells for low cost electrical production are not necessarily those with the highest efficiency, but those with a balance between low-cost production and efficiency high enough to minimize area-related balance of systems cost. Those companies with large scale manufacturing technology for coating inexpensive substrates may, in fact, ultimately be the lowest cost net electricity producers, even with cell efficiencies that are lower than those of single-crystal technologies.

Solar collector

It has been suggested that this article or section be merged into Solar thermal collector . (Discuss)

A solar collector is a device for extracting the energy of the sun not indirectly into a more usable or storable form. The energy in sunlight is in the form of electromagnetic radiation from the infrared (long) to the ultraviolet (short) wavelengths. The solar energy striking the earth's surface at any one time depends on weather conditions, as well as location and orientation of the surface, but overall, it averages about 1000 watts per square meter on a clear day with the surface directly perpendicular to the sun's rays. The best designed solar collectors are the ones that collect the most solars. Glazing is a common process used to increase the absorption rate of solars.

Solar Design

The solar heating system consists of the collector described above; a heat transfer circuit that includes the fluid and the means to circulate it; and a storage system including a heat exchanger (if the fluid cirulating through the collector is not the same liquid being used to heat the object of the system). The system may or may not include secondary distribution of heat among different storage reservoirs or users of the heat. The system can be used in a variety of ways, including warming domestic hot water, heating swimming pools, heating water for a radiator or floor-coil heating circuit, heating an industrial dryer, or providing input energy for a cooling system, among others. In addition, glazing is a process in which a thin layer of 5-hydroxymethylfurfural is applied to improve heat rejection at low light wavelengths. The heat is normally stored in insulated storage tanks full of water. Heat storage is usually intended to cover a day or two's requirements, but other concepts exist including seasonal storage (where summer solar energy is used for winter heating by just raising the temperature by a few degrees of several million liters of water (numerous pilot housing projects in Germany and elsewhere use this concept).

Solar System types

For solar heating of domestic hot water, two common system types are thermosyphon and pumped. In the thermosyphon system, a storage tank is placed above the collector. As the water in the collector is heated, it will rise and naturally start to circulate around the tank. This draws in colder water from the bottom of the tank. This system is self-regulating and requires no moving parts or external energy, so is very attractive. Its main drawback is the need for the tank to be placed at a level higher than the collector, which may prove to be physically difficult. A pumped system uses a pump to circulate the water, so the tank can be positioned independently of the collector location. This system requires external energy to run the pump (though this can be solar, since the water should only be circulated when there is incident sunlight). It also requires control electronics to measure the temperature gradient across the collector and modulate the pump accordingly. Systems using solar electric pumping and controls are known as zero carbon solar while those using mains electricity are known as low carbon, since they typically have a 10-20% carbon drawback.

Solar Placement

A laundromat in California with solar collectors on the roof.Solar collectors can be mounted on a roof but need to face the sun, so a north-facing roof in the southern hemisphere, and a south-facing roof in the northern hemisphere is ideal. Collectors are usually also angled to suit the latitude of the location. Where sunshine is readily available, a 2 to 10 square metre array will provide all the hot water heating required for a typical family house. Such systems are a key feature of sustainable housing, since water and space heating is usually the largest single consumer of energy in households.

Solar thermal collectors

For more details on this topic, see Solar thermal collector. A solar thermal collector that stores heat energy is called a "batch" type system. Other types of solar thermal collectors do not store energy but instead use fluid circulation (usually water or an antifreeze solution) to transfer the heat for direct use or storage in an insulated reservoir. Water/glycol has a high thermal capacity and is therefore convenient to handle. The direct radiation is captured using a dark colored surface which absorbs the radiation as heat and conducts it to the transfer fluid. Metal makes a good thermal conductor, especially copper and aluminium. In high performance collectors, a "selective surface" is used in which the collector surface is coated with a material having properties of high-absorption and low-emissivity. The selective surface reduces heat-loss caused by infrared radiant emission from the collector to ambient. Another method of reducing radiant heat-loss employs a transparent window such as clear UV stabilized plastic or Low-emissivity glass plate. Again, Low-E materials are the most effective, particularly the type optimized for solar gain. Borosilicate glass or "Pyrex" (tm) has low-emissivity properties, which may be useful, particularly for solar cooking applications.

As it heats up, thermal losses from the collector itself will reduce its efficiency, resulting in increased radiation, primarily infrared. This is countered in two ways. First, a glass plate is placed above the collector plate which will trap the radiated heat within the airspace below it. This exploits the so-called greenhouse effect, which is in this case a property of the glass: it readily transmits solar radiation in the visible and ultraviolet spectrum, but does not transmit the lower frequency infrared re-radiation very well. The glass plate also traps air in the space, thus reducing heat losses by convection. The collector housing is also insulated below and laterally to reduce its heat loss. The second way efficiency is improved is by cooling the absorber plate. This is done by ensuring that the coldest available heat transfer fluid is circulated through the absorber, and with a sufficient flow rate. The fluid carries away the absorbed heat, thus cooling the absorber. The warmed fluid leaving the collector is either directly stored, or else passes through a heat exchanger to warm another tank of water, or is used to heat a building directly. The temperature differential across an efficient solar collector is usually only 10 or 20°C. While a large differential may seem impressive, it is in fact an indication of a less efficient design.

Solar cooker

In Ghana, Zouzugu villagers like this woman prevent dracunculiasis and other waterborne diseases by pasteurizing water in a CooKit solar cooker.A solar oven or solar cooker is a device which uses sunlight as its energy source. Because they use no fuel and they cost nothing to run, humanitarian organizations are promoting their use worldwide to help slow deforestation and desertification, caused by using wood as fuel for cooking. Solar cookers are also sometimes used in outdoor cooking, especially in situations where minimal fuel consumption or fire risk are considered highly important.

Solar Types

There are many different types of solar cookers. In fact, there are over 65 major designs and hundreds of variations of them.Review of Solar Cookers The basic principles of all solar cookers are:

Concentrating sunlight: Some device, usually a mirror or some type of reflective metal, is used to concentrate light and heat from the sun into a small cooking area, making the energy more concentrated and therefore more potent. Converting light to heat: Any black on the inside of a solar cooker, as well as certain materials for pots, will improve the effectiveness of turning light into heat. A black pan will absorb almost all of the sun's light and turn it into heat, substantially improving the effectiveness of the cooker. Also, the better a pan conducts heat, the faster the oven will work.

Trapping heat: Isolating the air inside the cooker from the air outside the cooker makes an important difference. Using a clear solid, like a plastic bag or a glass cover, will allow light to enter, but once the light is absorbed and converted to heat, a plastic bag or glass cover will trap the heat inside using the Greenhouse Effect. This makes it possible to reach similar temperatures on cold and windy days as on hot days.

Alone, each of these strategies for heating something with the sun is fairly ineffective, but most solar cookers use two or all three of these strategies in combination to get temperatures sufficient for cooking.

The top can usually be removed to allow dark pots containing food to be placed inside. The box usually has one or more reflectors with aluminum foil or other reflective material to bounce extra light into the interior of the box. Cooking containers and the inside bottom of the cooker should be dark-colored or black. The inside walls should be reflective to reduce radiative heat loss and bounce the light towards the pots and the dark bottom, which is in contact with the pots.

Solar Box cookers

The inside insulator for the solar box cooker has to be able to withstand temperatures up to 150°C (300 °F) without melting or off-gassing. Crumpled newspapers, wool, rags, dry grass, sheets of cardboard, etc. can be used to insulate the walls of the cooker, but since most of the heat escapes through the top glass or plastic, very little insulation in the walls is necessary. The transparent top is either glass, which is durable but hard to work with, or an oven cooking bag, which is lighter, cheaper, and easier to work with, but less durable. If dark pots and/or bottom trays cannot be located, these can be darkened either with flat-black spray paint (one that is non-toxic when warmed), black tempera paint, or soot from a fire.

The solar box cooker typically reaches a temperature of 150 °C (300 °F). This is not as hot as a standard oven, but still hot enough to cook food over a somewhat longer period of time. Food containing moisture cannot get much hotter than 100 °C (212 °F) in any case, so it is not necessary to cook at the high temperatures indicated in standard cookbooks. Because the food does not reach too high a temperature, it can be safely left in the cooker all day without burning. It is best to start cooking before noon, though. Depending on the latitude and weather, food can be cooked either early or later in the day. The cooker can be used to warm food and drinks and can also be used to pasteurize water or milk.

Solar box cookers can be made of locally available materials or be manufactured in a factory for sale. They range from small cardboard devices, suitable for cooking a single meal when the sun is shining, to wood and glass boxes built into the sunny side of a house. Although invented by Horace de Saussure, a Swiss naturalist, as early as 1767, solar box cookers have only gained popularity since the 1970s. These surprisingly simple and useful appliances are seen in growing numbers in almost every country of the world. An index of detailed wiki pages for each country can be found here.

Solar Panel cookers

Panel solar cookers are very inexpensive solar cookers that use shiny panels to direct sunlight to a cooking pot that is enclosed in a clear plastic bag. A common model is the CooKit. Developed in 1994 by Solar Cookers International, it is often produced locally by pasting a reflective material, such as aluminum foil, onto a cut and folded backing, usually corrugated cardboard. It is lightweight and folds for storage. When completely unfolded, it measures about three feet by four feet (1 m by 1.3 m). Using materials purchased in bulk, the typical cost is about US$5. However, CooKits can also be made entirely from reclaimed materials, including used carboard boxes and foil from the inside of cigarette boxes.

The CooKit is considered a low-to-moderate temperature solar cooker, easily reaching temperatures high enough to pasteurize water or cook grains such as rice. On a sunny day, one CooKit can collect enough solar energy to cook rice, meat or vegetables to feed a family with up to three or four children. Larger families use two or more cookers.

To use a panel cooker, it is folded into a bowl shape. Food is placed in a dark-colored pot, covered with a tightly fitted lid. The pot is placed in a clear plastic bag and tied, clipped, or folded shut. The panel cooker is placed in direct sunlight until the food is cooked, which usually requires several hours for a full family-sized meal. For faster cooking, the pot can be raised on sticks or wires to allow the heated air to circulate underneath it.

High-temperature plastic bags (oven roasting bags) can be re-used for more than a month, but any plastic bag will work, if measures (such as sticks or wires) are taken to keep the bag from touching the hot cooking pot and melting to it. The purpose of the plastic bag is to trap heated air next to the pot; it may not be needed on very bright, windless days.

The HotPot cooking vessel consists of a dark pot suspended inside a clear pot with a lidA recent development is the HotPot developed by US NGO Solar Household Energy, Inc. The cooking vessel in this cooker is a large clear pot with a clear lid into which a dark pot is suspended. This design has the advantage of very even heating since the sun is able to shine onto the sides and the bottom of the pot during cooking. An added advantage is that the clear lid allows the food to be observed while it is cooking without removing the lid. The HotPot provides an alternative to using plastic bags in a panel cooker.

Image:Sunlight 071108 big.gif New type of Panel CookerOne of the outstanding designs of Solar Panel Cookers has been presented by John Tilleman of the USA. This design won first prize in a competition. It is very easy to make and performs well. The performance could be improved by using a modified Diassana Enclosure for the cooking pot.

Solar kettles

Solar tea kettle, Norbulingka, TibetSolar kettles are solar thermal devices that can heat water to boiling point through the reliance on solar energy alone. Typically they use evacuated solar glass tube technology to capture, accumulate and store solar energy needed to power the kettle. Besides heating liquids, since the stagnating temperature of solar vacuum glass tubes is a high 220 degrees Celsius (425 °F), solar kettles can also deliver dry heat and function as ovens and autoclaves. Moreover, since solar vacuum glass tubes work on accumulated rather than concentrated solar thermal energy, solar kettles only need diffused sunlight to work and needs no sun tracking at all. If solar kettles use solar vacuum tubes technologies, the vacuum insulating properties will keep previously heated water hot throughout the night.

Parabolic Solar cookers

Although these types of solar cookers can cook as well as a conventional oven, they are difficult to construct. Parabolic cookers reach high temperatures and cook quickly, but require frequent adjustment and supervision for safe operation. Several hundred thousand exist, mainly in China. They are especially useful for large-scale institutional cooking.

The solar bowl is a unique concentrating technology used by the Solar Kitchen in Auroville, India. Unlike nearly all concentrating technologies that use tracking reflector systems, the solar bowl uses a stationary spherical reflector. This reflector focuses light along a line perpendicular to the sphere's surface and a computer control system moves the receiver to intersect this line. Steam is produced in the solar bowl's receiver at temperatures reaching 150 °C and then used for process heat in the kitchen where 2,000 meals are prepared daily.

Hybrid Solar cookers

A hybrid solar oven is a type of solar oven that uses both the regular elements of a solar box cooker as well as a conventional electrical heating element for cloudy days or nighttime cooking. Hybrid solar ovens are therefore more independent. However, they lack the cost advantages of some other types of solar cookers, and so they have not caught on as much in third world countries.

A hybrid solar grill consists of an adjustable parabolic reflector suspended in a tripod with a movable grill surface. These outperform solar box cookers in temperature range and cooking times. When solar energy is not available, the design uses any conventional fuel as a heat source, including gas, electricity, wood, etc. The tripod hybrid grill is revolutionary in that many, if not all, of the parts required to build them can be scavenged from commonly thrown away items.

Using a solar cooker

The different kinds of solar cookers have somewhat different methods for use, but most follow the same basic principles.

Food is prepared as it would be for an oven or stove top. Because food cooks faster when it is in smaller pieces, solar cookers usually cut the food into smaller pieces than they might otherwise. For example, potatoes are usually cut into bite-sized pieces rather than being roasted whole. Bread is usually baked as individual rolls instead of large loaves. When a food, such as rice, needs to be cooked in water, the minimum necessary amount of water is used.

The prepared food is placed in an appropriately sized heat-proof container. Efficient containers are not significantly larger than necessary to hold the food and are usually shallow. The most efficient containers are made of thin, dull metal, dark in color, with a lid that covers the food and reduces moisture loss, but does not completely seal. Glass containers and even plain paper bags are also used. Pottery and thick metal (such as cast iron) cook food more slowly, but retain their heat better when the sunlight has declined. For very simple cooking, such as melting butter or cheese, a lid may not be needed and the food may be placed on an uncovered tray or in a bowl. If several foods are to be cooked separately, then they are placed in different containers.

The container of food is placed inside the solar cooker, perhaps elevated on a brick, rocks, metal trivet, or other heat sink, and the solar cooker is placed in direct sunlight. If the solar cooker is entirely in direct sunlight, then the shadow of the solar cooker will not overlap with the shadow of any nearby object. Foods that cook quickly may be added to the solar cooker later. Rice for a mid-day meal might be started early in the morning, with vegetables, cheese, or meat added to the solar cooker in the middle of the morning. Depending on the size of the solar cooker and the number and quantity of cooked foods, a family may use one or more solar cookers.

The solar cooker is turned towards the sun and left until the food is cooked. Unlike cooking on a stove or over a fire, which may require more than an hour of constant supervision, food in a solar cooker is generally not stirred or turned over, both because it is unnecessary and because opening the solar cooker allows the trapped heat to escape and thereby slows the cooking process. If wanted, the solar cooker may be checked every one to two hours, to turn the cooker to face the sun more precisely and to ensure that shadows from nearby buildings or plants have not blocked the sunlight. If the food will be left untended for many hours during the day, then the solar cooker is often turned to face the point where the sun will be when it is higher in the sky, instead of towards its current position.

The cooking time depends primarily on the equipment beings used, the amount of sunlight at the time, and the quantity of food that needs to be cooked. Air temperature, wind, and latitude also affect performance. Food cooks faster in the two hours before and after the local solar noon than it does in either the early morning or the late afternoon. Larger quantities of food, and food in larger pieces, take longer to cook. As a result, only general figures can be given for cooking time. For a small solar panel cooker, it might be possible to melt butter in 15 minutes, to bake cookies in 2 hours, and to cook rice for four people in 4 hours. However, depending on the local conditions and the solar cooker type, these projects could take half as long, or twice as long.

It is difficult to burn food in a solar cooker. Food that has been cooked even an hour longer than necessary is usually indistinguishable from minimally cooked food. The exception to this rule is some green vegetables, which quickly change from a perfectly cooked bright green to olive drab, while still retaining the desirable texture.

For most foods, such as rice, the typical person would be unable to tell how it was cooked from looking at the final product. There are some differences, however: Bread and cakes brown on their tops instead of on bottom. Compared to cooking over a fire, the food does not have a smoky flavor.

Certain foods require different cooking techniques. For example, to fry an egg in a solar cooker, a common method pre-heats an empty, heavy, dark-colored metal skillet in the solar cooker. Then oil or butter is melted in the pan until sizzling hot. Finally, an egg is added to the pan, where it can cook almost as quickly as it might on a stove top, largely from the stored heat in the pan. Cakes are often baked in a pre-heated solar cooker, perhaps while sitting on a hot brick.

Solar Advantages

Solar ovens are just one part of the alternative energy picture, but one that is accessible to a great majority of people. A reliable solar oven can be built from everyday materials in just a few hours or purchased ready-made.

Solar ovens can be used to prepare anything that can be made in a conventional oven or stove from baked bread to steamed vegetables to roasted meat. Since solar ovens are placed outside, they do not contribute unwanted heat inside houses. Nearly three-quarters of US households prepare at least one hot meal per day; one-third prepare two or more. Many of these meals could be made in a less fuel-intensive way using a solar oven.

The World Health Organization reports that cooking with fuel wood is the equivalent of smoking two packs of cigarettes a day. Inhalation of smoke from cooking fires causes respiratory diseases and death. One of the solutions advocated to address this problem is solar cooking which makes no smoke at all.

In advanced countries, the environmental advantages, a desire for energy independence, and not heating up the house on a hot day are usually cited as advantages. In the developing world, other advantages include:

lower cost compared to firewood or cooking oil; greater safety for children and the cook compared to a fire or stove; lower likelihood of starting a fire that could destroy a family's home; and less time spent cooking compared to tending a fire or stove.

Solar Disadvantages

Solar cookers provide hot food during or shortly after the hottest part of the day, when people are less inclined to eat a hot meal. However, a thick pan that conducts heat slowly (such as Cast Iron) will lose heat at a slower rate, and that, combined with the insulation of the oven or an insulated basket, can be used to keep food warm well into the evening.

Solar cookers take longer to cook food compared to an oven. Using a solar oven therefore requires that food preparation be started several hours before the meal. However, it requires less hands-on time cooking, so this is often considered a reasonable trade-off.

Solar cooking projects

Solar Bakeries in Lesotho

Michael Hönes of Germany has established solar cooking in Lesotho, enabling small groups of women to build up community bakeries using solar ovens.

Solar at Darfur refugee camps

Cardboard, aluminum foil, and plastic bags for well over 10,000 solar cookers have been donated to the Iridimi refugee camp and Touloum refugee camps in Chad by the combined efforts of the Jewish World Watch, the Dutch foundation KoZon, and Solar Cookers International. The refugees construct the cookers themselves, using the donated supplies and locally purchased Arabic gum, and use them for midday and evening meals. The goal of this project was to reduce the Darfuri women's need to leave the relative safety of the camp to gather firewood, which exposed them to a high risk of being beaten, raped, kidnapped, or murdered. It has also significantly reduced the amount of time women spend tending open fires each day, with the results that they are healthier and they have more time to grow vegetables for their families and make handicrafts for export.

Indian solar cooker village

Bysanivaripalle, a silk-producing village that is 125 km (80 mi) northwest of Tirupati in the Indian state of in Andhra Pradesh, is the first of its kind: an entire village that uses only solar cooking. Intersol, an Austrian non-governmental organisation, sponsored the provision of powerful "Sk-14" parabolic solar cookers in 2004

Solar energy

The parabolic dish engine system, which concentrates solar powerRenewable energy

Biofuels - Biomass - Geothermal

Hydro power - Solar power - Tidal power

Wave power - Wind power

Solar energy is the light and radiant heat from the Sun that influences Earth's climate and weather and sustains life. Solar power is the rate of solar energy at a point in time; it is sometimes used as a synonym for solar energy or more specifically to refer to electricity generated from solar radiation. Since ancient times solar energy has been harnessed for human use through a range of technologies. Solar radiation along with secondary solar resources such as wind and wave power, hydroelectricity and biomass account for most of the available flow of renewable energy on Earth.

Solar energy technologies can provide electrical generation by heat engine or photovoltaic means, daylighting, hot water, and space heating in active and passive solar buildings; potable water via distillation and disinfection, space cooling by absorption or vapor-compression refrigeration, thermal energy for cooking, and high temperature process heat for industrial purposes.

Energy from the Sun

About half the incoming solar energy reaches the earth's surface.The Earth receives 174 petawatts (PW) of incoming solar radiation (insolation) at the upper atmosphere. Approximately 30% is reflected back to space while the rest is absorbed by clouds, oceans and land masses. The spectrum of solar light at the Earth's surface is mostly spread across the visible and near-infrared ranges with a small part in the near-ultraviolet.

The absorbed solar light heats the land surface, oceans and atmosphere. The warm air containing evaporated water from the oceans rises, driving atmospheric circulation or convection. When this air reaches a high altitude, where the temperature is low, water vapor condenses into clouds, which rain onto the earth's surface, completing the water cycle. The latent heat of water condensation amplifies convection, producing atmospheric phenomena such as cyclones and anti-cyclones. Wind is a manifestation of the atmospheric circulation driven by solar energy. Sunlight absorbed by the oceans and land masses keeps the surface at an average temperature of 14 °C. The conversion of solar energy into chemical energy via photosynthesis produces food, wood and the biomass from which fossil fuels are derived.

Yearly energy resources & annual energy consumption (TWh)

Solar energy absorbed by atmosphere, oceans and Earth 751,296,000.0

Wind energy (technical potential) 221,000.0

Electricity (2005) -45.2

Primary energy use (2005) -369.7

Solar radiation along with secondary solar resources such as wind and wave power, hydroelectricity and biomass account for 99.97% of the available renewable energy on Earth. The total solar energy absorbed by Earth's atmosphere, oceans and land masses is approximately 3,850 zettajoules (ZJ) per year. In 2002, this was more energy in one hour than the world used in one year. Photosynthesis captures approximately 3 ZJ per year in biomass. The amount of solar energy reaching the surface of the planet is so vast that in one year it is about twice as much as will ever be obtained from all of the Earth's non-renewable resources of coal, oil, natural gas, and mined uranium combined.

From the table of resources it would appear that solar, wind or biomass would be sufficient to supply all of our energy needs, however, the increased use of biomass has had a negative effect on global warming and dramatically increased food prices by diverting forests and crops into biofuel production. As intermittent resources, solar and wind raise other issues.

Applications of solar energy technology

Average insolation showing land area (small black dots) required to replace the total world energy supply with solar electricity. Insolation for most people is from 150 to 300 W/m^2 or 3.5 to 7.0 kWh/m^2/day.Solar energy refers primarily to the use of solar radiation for practical ends. All other renewable energies other than geothermal derive their energy from energy received from the sun.

Solar technologies are broadly characterized as either passive or active depending on the way they capture, convert and distribute sunlight. Active solar techniques use photovoltaic panels, pumps, and fans to convert sunlight into useful outputs. Passive solar techniques include selecting materials with favorable thermal properties, designing spaces that naturally circulate air, and referencing the position of a building to the Sun. Active solar technologies increase the supply of energy and are considered supply side technologies, while passive solar technologies reduce the need for alternate resources and are generally considered demand side technologies.

Architecture and urban planning

Darmstadt University of Technology won the 2007 Solar Decathlon in Washington, D.C. with this passive house designed specifically for the humid and hot subtropical climate Sunlight has influenced building design since the beginning of architectural history. Advanced solar architecture and urban planning methods were first employed by the Greeks and Chinese, who oriented their buildings toward the south to provide light and warmth.

The common features of passive solar architecture are orientation relative to the Sun, compact proportion (a low surface area to volume ratio), selective shading (overhangs) and thermal mass. When these features are tailored to the local climate and environment they can produce well-lit spaces that stay in a comfortable temperature range. Socrates' Megaron House is a classic example of passive solar design. The most recent approaches to solar design use computer modeling tying together solar lighting, heating and ventilation systems in an integrated solar design package. Active solar equipment such as pumps, fans and switchable windows can complement passive design and improve system performance.

Urban heat islands (UHI) are metropolitan areas with higher temperatures than that of the surrounding environment. The higher temperatures are a result of increased absorption of the Solar light by urban materials such as asphalt and concrete, which have lower albedos and higher heat capacities than those in the natural environment. A straightforward method of counteracting the UHI effect is to paint buildings and roads white and plant trees. Using these methods, a hypothetical "cool communities" program in Los Angeles has projected that urban temperatures could be reduced by approximately 3 °C at an estimated cost of US$1 billion, giving estimated total annual benefits of US$530 million from reduced air-conditioning costs and healthcare savings.

Agriculture and horticulture

Greenhouses like these in the Netherlands' Westland municipality grow vegetables, fruits and flowers.Agriculture seeks to optimize the capture of solar energy in order to optimize the productivity of plants. Techniques such as timed planting cycles, tailored row orientation, staggered heights between rows and the mixing of plant varieties can improve crop yields. While sunlight is generally considered a plentiful resource, the exceptions highlight the importance of solar energy to agriculture. During the short growing seasons of the Little Ice Age, French and English farmers employed fruit walls to maximize the collection of solar energy. These walls acted as thermal masses and accelerated ripening by keeping plants warm. Early fruit walls were built perpendicular to the ground and facing south, but over time, sloping walls were developed to make better use of sunlight. In 1699, Nicolas Fatio de Duillier even suggested using a tracking mechanism which could pivot to follow the Sun. Applications of solar energy in agriculture aside from growing crops include pumping water, drying crops, brooding chicks and drying chicken manure.

Greenhouses convert solar light to heat, enabling year-round production and the growth (in enclosed environments) of specialty crops and other plants not naturally suited to the local climate. Primitive greenhouses were first used during Roman times to produce cucumbers year-round for the Roman emperor Tiberius. The first modern greenhouses were built in Europe in the 16th century to keep exotic plants brought back from explorations abroad. Greenhouses remain an important part of horticulture today, and plastic transparent materials have also been used to similar effect in polytunnels and row covers.

Solar lighting

Daylighting features such as this oculus at the top of the Pantheon in Rome have been in use since antiquity.The history of lighting is dominated by the use of natural light. The Romans recognized a right to light as early as the 6th century and English law echoed these judgments with the Prescription Act of 1832. In the 20th century artificial lighting became the main source of interior illumination but daylighting techniques and hybrid solar lighting solutions are ways to reduce energy consumption.

Daylighting systems collect and distribute sunlight to provide interior illumination. This passive technology directly offsets energy use by replacing artificial lighting, and indirectly offsets non-solar energy use by reducing the need for air-conditioning. Although difficult to quantify, the use of natural lighting also offers physiological and psychological benefits compared to artificial lighting. Daylighting design implies careful selection of window types, sizes and orientation; exterior shading devices may be considered as well. Individual features include sawtooth roofs, clerestory windows, light shelves, skylights and light tubes. They may be incorporated into existing structures, but are most effective when integrated into a solar design package that accounts for factors such as glare, heat flux and time-of-use. When daylighting features are properly implemented they can reduce lighting-related energy requirements by 25%.

Hybrid solar lighting is an active solar method of providing interior illumination. HSL systems collect sunlight using focusing mirrors that track the Sun and use optical fibers to transmit it inside the building to supplement conventional lighting. In single-story applications these systems are able to transmit 50% of the direct sunlight received.

Solar lights that charge during the day and light up at dusk are a common sight along walkways.

Although daylight saving time is promoted as a way to use sunlight to save energy, recent research has been limited and reports contradictory results: several studies report savings, but just as many suggest no effect or even a net loss, particularly when gasoline consumption is taken into account. Electricity use is greatly affected by geography, climate and economics, making it hard to generalize from single studies.

Solar thermal

Solar thermal technologies can be used for water heating, space heating, space cooling and process heat generation.

Water heating

Solar water heaters facing the Sun to maximize gainSolar hot water systems use sunlight to heat water. In low geographical latitudes (below 40 degrees) from 60 to 70% of the domestic hot water use with temperatures up to 60 °C can be provided by solar heating systems. The most common types of solar water heaters are evacuated tube collectors (44%) and glazed flat plate collectors (34%) generally used for domestic hot water; and unglazed plastic collectors (21%) used mainly to heat swimming pools.

As of 2007, the total installed capacity of solar hot water systems is approximately 154 GW. China is the world leader in their deployment with 70 GW installed as of 2006 and a long term goal of 210 GW by 2020. Israel and Cypress are the per capita leaders in the use of solar hot water systems with over 90% of homes using them. In the United States, Canada and Australia heating swimming pools is the dominant application of solar hot water with an installed capacity of 18 GW as of 2005.

Heating, cooling and ventilation

MIT's Solar House #1, built in 1939, used seasonal thermal storage for year-round heating.In the United States, heating, ventilation and air conditioning (HVAC) systems account for 30% (4.65 EJ) of the energy used in commercial buildings and nearly 50% (10.1 EJ) of the energy used in residential buildings. Solar heating, cooling and ventilation technologies can be used to offset a portion of this energy.

Thermal mass is any material that can be used to store heat heat from the Sun in the case of solar energy. Common thermal mass materials include stone, cement and water. Historically they have been used in arid climates or warm temperate regions to keep buildings cool by absorbing solar energy during the day and radiating stored heat to the cooler atmosphere at night. However they can be used in cold temperate areas to maintain warmth as well. The size and placement of thermal mass depend on several factors such as climate, daylighting and shading conditions. When properly incorporated, thermal mass maintains space temperatures in a comfortable range and reduces the need for auxiliary heating and cooling equipment.

A solar chimney (or thermal chimney, in this context) is a passive solar ventilation system composed of a vertical shaft connecting the interior and exterior of a building. As the chimney warms, the air inside is heated causing an updraft that pulls air through the building. Performance can be improved by using glazing and thermal mass materials in a way that mimics greenhouses.

Deciduous trees and plants have been promoted as a means of controlling solar heating and cooling. When planted on the southern side of a building, their leaves provide shade during the summer, while the bare limbs allow light to pass during the winter. Since bare, leafless trees shade 1/3 to 1/2 of incident solar radiation, there is a balance between the benefits of summer shading and the corresponding loss of winter heating. In climates with significant heating loads, deciduous trees should not be planted on the southern side of a building because they will interfere with winter solar availability. They can, however, be used on the east and west sides to provide a degree of summer shading without appreciably affecting winter solar gain.

Water treatment

Application of SODIS technology in Indonesia to water disinfectionSolar distillation can be used to make saline or brackish water potable. The first recorded instance of this was by 16th century Arab alchemists. A large-scale solar distillation project was first constructed in 1872 in the Chilean mining town of Las Salinas. The plant, which had solar collection area of 4,700 m², could produce up to 22,700 L per day and operated for 40 years. Individual still designs include single-slope, double-slope (or greenhouse type), vertical, conical, inverted absorber, multi-wick, and multiple effect. These stills can operate in passive, active, or hybrid modes. Double-slope stills are the most economical for decentralized domestic purposes, while active multiple effect units are more suitable for large-scale applications.

Solar water disinfection (SODIS) involves exposing water-filled plastic polyethylene terephthalate (PET) bottles to sunlight for several hours. Exposure times vary depending on weather and climate from a minimum of six hours to two days during fully overcast conditions. SODIS is recommended by the World Health Organization as a viable method for household water treatment and safe storage. Over two million people in developing countries use SODIS for their daily drinking water.

Small scale solar powered sewerage treatment plantSolar energy may be used in a water stabilisation pond to treat waste water without chemicals or electricity. A further environmental advantage is that algae grow in such ponds and consume carbon dioxide in photosynthesis.

Cooking

The Solar Bowl in Auroville, India, concentrates sunlight on a movable receiver to produce steam for cooking.Solar cookers use sunlight for cooking, drying and pasteurization. They can be grouped into three broad categories: box cookers, panel cookers and reflector cookers. The simplest solar cooker the box cooker first built by Horace de Saussure in 1767. A basic box cooker consists of an insulated container with a transparent lid. It can be used effectively with partially overcast skies and will typically reach temperatures of 90-150 °C. Panel cookers use a reflective panel to direct sunlight onto an insulated container and reach temperatures comparable to box cookers. Reflector cookers use various concentrating geometries (dish, trough, Fresnel mirrors) to focus light on a cooking container. These cookers reach temperatures of 315 °C and above but require direct light to function properly and must be repositioned to track the Sun.

The solar bowl is a concentrating technology employed by the Solar Kitchen in Auroville, India, where a stationary spherical reflector focuses light along a line perpendicular to the sphere's interior surface, and a computer control system moves the receiver to intersect this line. Steam is produced in the receiver at temperatures reaching 150 °C and then used for process heat in the kitchen.

A reflector developed by Wolfgang Scheffler in 1986 is used in many solar kitchens. Scheffler reflectors are flexible parabolic dishes that combine aspects of trough and power tower concentrators. Polar tracking is used to follow the Sun's daily course and the curvature of the reflector is adjusted for seasonal variations in the incident angle of sunlight. These reflectors can reach temperatures of 450-650 °C and have a fixed focal point, which simplifies cooking. The world's largest Scheffler reflector system in Abu Road, Rajasthan, India is capable of cooking up to 35,000 meals a day. As of 2008, over 2,000 large Scheffler cookers had been built worldwide.

Process heat

STEP parabolic dishes used for steam production and electrical generationSolar concentrating technologies such as parabolic dish, trough and Scheffler reflectors can provide process heat for commercial and industrial applications. The first commercial system was the Solar Total Energy Project (STEP) in Shenandoah, Georgia, USA where a field of 114 parabolic dishes provided 50% of the process heating, air conditioning and electrical requirements for a clothing factory. This grid-connected cogeneration system provided 400 kW of electricity plus thermal energy in the form of 401 kW steam and 468 kW chilled water, and had a one hour peak load thermal storage.

Evaporation ponds are shallow pools that concentrate dissolved solids through evaporation. The use of evaporation ponds to obtain salt from sea water is one of the oldest applications of solar energy. Modern uses include concentrating brine solutions used in leach mining and removing dissolved solids from waste streams.

Clothes lines, clotheshorses, and clothes racks dry clothes through evaporation by wind and sunlight without consuming electricity or gas. In some states of the United States legislation protects the "right to dry" clothes.

Unglazed transpired collectors (UTC) are perforated sun-facing walls used for preheating ventilation air. UTCs can raise the incoming air temperature up to 22 °C and deliver outlet temperatures of 45-60 °C. The short payback period of transpired collectors (3 to 12 years) makes them a more cost-effective alternative than glazed collection systems. As of 2003, over 80 systems with a combined collector area of 35,000 m² had been installed worldwide, including an 860 m² collector in Costa Rica used for drying coffee beans and a 1,300 m² collector in Coimbatore, India used for drying marigolds.

Solar electricity

Sunlight can be converted into electricity using photovoltaics (PV), concentrating solar power (CSP), and various experimental technologies. PV has mainly been used to power small and medium-sized applications, from the calculator powered by a single solar cell to off-grid homes powered by a photovoltaic array. For large-scale generation, CSP plants like SEGS have been the norm but recently multi-megawatt PV plants are becoming common. Completed in 2007, the 14 MW power station in Clark County, Nevada and the 20 MW site in Beneixama, Spain are characteristic of the trend toward larger photovoltaic power stations in the US and Europe.

Photovoltaics

11 MW Serpa solar power plant in PortugalA solar cell, or photovoltaic cell (PV), is a device that converts light into direct current using the photoelectric effect. The first solar cell was constructed by Charles Fritts in the 1880s. Although the prototype selenium cells converted less than 1% of incident light into electricity, both Ernst Werner von Siemens and James Clerk Maxwell recognized the importance of this discovery. Following the work of Russell Ohl in the 1940s, researchers Gerald Pearson, Calvin Fuller and Daryl Chapin created the silicon solar cell in 1954. These early solar cells cost 286 USD/watt and reached efficiencies of 4.5-6%.

The earliest significant application of solar cells was as a back-up power source to the Vanguard I satellite, which allowed it to continue transmitting for over a year after its chemical battery was exhausted. The successful operation of solar cells on this mission was duplicated in many other Soviet and American satellites, and by the late 1960s, PV had become the established source of power for them. Photovoltaics went on to play an essential part in the success of early commercial satellites such as Telstar, and they remain vital to the telecommunications infrastructure today.

The high cost of solar cells limited terrestrial uses throughout the 1960s. This changed in the early 1970s when prices reached levels that made PV generation competitive in remote areas without grid access. Early terrestrial uses included powering telecommunication stations, off-shore oil rigs, navigational buoys and railroad crossings. These off-grid applications have proven very successful and accounted for over half of worldwide installed capacity until 2004.

Building-integrated photovoltaics cover the roofs of the increasing number of homes.The 1973 oil crisis stimulated a rapid rise in the production of PV during the 1970s and early 1980s. Economies of scale which resulted from increasing production along with improvements in system performance brought the price of PV down from 100 USD/watt in 1971 to 7 USD/watt in 1985. Steadily falling oil prices during the early 1980s led to a reduction in funding for photovoltaic R&D and a discontinuation of the tax credits associated with the Energy Tax Act of 1978. These factors moderated growth to approximately 15% per year from 1984 through 1996.

Since the mid-1990s, leadership in the PV sector has shifted from the US to Japan and Germany. Between 1992 and 1994 Japan increased R&D funding, established net metering guidelines, and introduced a subsidy program to encourage the installation of residential PV systems. As a result, PV installations in the country climbed from 31.2 MW in 1994 to 318 MW in 1999, and worldwide production growth increased to 30% in the late 1990s.

Germany has become the leading PV market worldwide since revising its Feed-in tariff system as part of the Renewable Energy Sources Act. Installed PV capacity has risen from 100 MW in 2000 to approximately 4,150 MW at the end of 2007. Spain has become the third largest PV market after adopting a similar feed-in tariff structure in 2004, while France, Italy, South Korea and the US have seen rapid growth recently due to various incentive programs and local market conditions.

Concentrating solar power

Solar troughs are the most widely deployed and the most cost-effective CSP technology.Concentrated sunlight has been used to perform useful tasks since the time of ancient China. A legend claims that Archimedes used polished shields to concentrate sunlight on the invading Roman fleet and repel them from Syracuse. Auguste Mouchout used a parabolic trough to produce steam for the first solar steam engine in 1866, and subsequent developments led to the use of concentrating solar-powered devices for irrigation, refrigeration and locomotion.

Concentrating Solar Power (CSP) systems use lenses or mirrors and tracking systems to focus a large area of sunlight into a small beam. The concentrated light is then used as a heat source for a conventional power plant. A wide range of concentrating technologies exists; the most developed are the solar trough, parabolic dish and solar power tower. These methods vary in the way they track the Sun and focus light. In all these systems a working fluid is heated by the concentrated sunlight, and is then used for power generation or energy storage.

The PS10 concentrates sunlight from a field of heliostats on a central tower.A solar trough consists of a linear parabolic reflector that concentrates light onto a receiver positioned along the reflector's focal line. The reflector is made to follow the Sun during the daylight hours by tracking along a single axis. Trough systems provide the best land-use factor of any solar technology. The SEGS plants in California and Acciona's Nevada Solar One near Boulder City, Nevada are representatives of this technology.

A parabolic dish system consists of a stand-alone parabolic reflector that concentrates light onto a receiver positioned at the reflector's focal point. The reflector tracks the Sun along two axes. Parabolic dish systems give the highest efficiency among CSP technologies. The 50 kW Big Dish in Canberra, Australia is an example of this technology. The stirling solar dish combines a parabolic concentrating dish with a stirling heat engine which normally drives an electric generator. The advantages of stirling solar over photovoltaic cells are higher efficiency of converting sunlight into electricity and longer lifetime. A stirling engine has an approximate mean time before failure (MTBF) of 25 years.

A solar power tower uses an array of tracking reflectors (heliostats) to concentrate light on a central receiver atop a tower. Power towers are less advanced than trough systems but offer higher efficiency and better energy storage capability. The Solar Two in Barstow, California and the Planta Solar 10 in Sanlucar la Mayor, Spain are representatives of this technology.

Experimental solar power

A solar updraft tower (also known as a solar chimney or solar tower) consists of a large greenhouse that funnels into a central tower. As sunlight shines on the greenhouse, the air inside is heated, and expands. The expanding air flows toward the central tower, where a turbine converts the air flow into electricity. A 50 kW prototype was constructed in Ciudad Real, Spain and operated for eight years before decommissioning in 1989.

A solar pond is a pool of salt water (usually 1-2 m deep) that collects and stores solar energy. Solar ponds were first proposed by Dr. Rudolph Bloch in 1948 after he came across reports of a lake in Hungary in which the temperature increased with depth. This effect was due to salts in the lake's water, which created a "density gradient" that prevented convection currents. A prototype was constructed in 1958 on the shores of the Dead Sea near Jerusalem. The pond consisted of layers of water that successively increased from a weak salt solution at the top to a high salt solution at the bottom. This solar pond was capable of producing temperatures of 90 °C in its bottom layer and had an estimated solar-to-electric efficiency of two percent.

Thermoelectric, or "thermovoltaic" devices convert a temperature difference between dissimilar materials into an electric current. First proposed as a method to store solar energy by solar pioneer Mouchout in the 1800s, thermoelectrics reemerged in the Soviet Union during the 1930s. Under the direction of Soviet scientist Abram Ioffe a concentrating system was used to thermoelectrically generate power for a 1 hp engine. Thermogenerators were later used in the US space program as an energy conversion technology for powering deep space missions such as Cassini, Galileo and Viking. Research in this area is focused on raising the efficiency of these devices from 7-8% to 15-20%.

Space solar power systems would use a large solar array in geosynchronous orbit to collect sunlight and beam this energy in the form of microwave radiation to receivers (rectennas) on Earth for distribution. This concept was first proposed by Dr. Peter Glaser in 1968 and since then a wide variety of systems have been studied with both photovoltaic and concentrating solar thermal technologies being proposed. Although still in the concept stage, these systems offer the possibility of delivering power approximately 96% of the time. In 2008, John C. Mankins, a former NASA scientist, successfully used radio waves to send solar power between two Hawaiian islands in an experiment funded by the Discovery Channel. Mankins claims that this "proves the technology exists to beam solar power from satellites back to Earth."

Solar chemical

Solar chemical processes use solar energy to drive chemical reactions. These processes offset energy that would otherwise come from an alternate source and can convert solar energy into storable and transportable fuels. Solar induced chemical reactions can be divided into thermochemical or photochemical.

Hydrogen production technologies been a significant area of solar chemical research since the 1970s. Aside from electrolysis driven by photovoltaic or photochemical cells, several thermochemical processes have also been explored. One such route uses concentrators to split water into oxygen and hydrogen at high temperatures (2300-2600 °C). Another approach uses the heat from solar concentrators to drive the steam reformation of natural gas thereby increasing the overall hydrogen yield compared to conventional reforming methods. Thermochemical cycles characterized by the decomposition and regeneration of reactants present another avenue for hydrogen production. The Solzinc process under development at the Weizmann Institute uses a 1 MW solar furnace to decompose zinc oxide (ZnO) at temperatures above 1200 °C. This initial reaction produces pure zinc, which can subsequently be reacted with water to produce hydrogen.

Sandia's Sunshine to Petrol (S2P) technology uses the high temperatures generated by concentrating sunlight along with a zirconia/ferrite catalyst to break down atmospheric carbon dioxide into oxygen and carbon monoxide (CO). The carbon monoxide can then be used to synthesize conventional fuels such as methanol, gasoline and jet fuel.

A photogalvanic device is a type of battery in which the cell solution (or equivalent) forms energy-rich chemical intermediates when illuminated. These energy-rich intermediates can potentially be stored and subsequently reacted at the electrodes to produce an electric potential. The ferric-thionine chemical cell is an example of this technology.

Photoelectrochemical cells or PECs consist of a semiconductor, typically titanium dioxide or related titanates, immersed in an electrolyte. When the semiconductor is illuminated an electrical potential develops. There are two types of photoelectrochemical cells: photoelectric cells that convert light into electricity and photochemical cells that use light to drive chemical reactions such as electrolysis.

Solar vehicles

Australia hosts the World Solar Challenge where solar cars like the Nuna3 race through a 3,021 km (1,877 mi) course from Darwin to Adelaide.Development of a solar powered car has been an engineering goal since the 1980s. The World Solar Challenge is a biannual solar-powered car race, where teams from universities and enterprises compete over 3,021 kilometres (1,877 mi) across central Australia from Darwin to Adelaide. In 1987, when it was founded, the winner's average speed was 67 kilometres per hour (42 mph) and by 2007 the winner's average speed had improved to 90.87 kilometres per hour (56.46 mph). The North American Solar Challenge and the planned South African Solar Challenge are comparable competitions that reflect an international interest in the engineering and development of solar powered vehicles.

Some vehicles use solar panels for auxiliary power, such as for air conditioning, to keep the interior cool, thus reducing fuel consumption.

In 1975, the first practical solar boat was constructed in England. By 1995, passenger boats incorporating PV panels began appearing and are now used extensively. In 1996, Kenichi Horie made the first solar powered crossing of the Pacific Ocean, and the sun21 catamaran made the first solar powered crossing of the Atlantic Ocean in the winter of 2006-2007. There are plans to circumnavigate the globe in 2010.

Helios UAV in solar powered flightIn 1974, the unmanned Sunrise II plane made the first solar flight. On 29 April 1979, the Solar Riser made the first flight in a solar powered, fully controlled, man carrying flying machine, reaching an altitude of 40 feet (12 m). In 1980, the Gossamer Penguin made the first piloted flights powered solely by photovoltaics. This was quickly followed by the Solar Challenger which crossed the English Channel in July 1981. In 1990 Eric Raymond in 21 hops flew from California to North Carolina using solar power. Developments then turned back to unmanned aerial vehicles (UAV) with the Pathfinder (1997) and subsequent designs, culminating in the Helios which set the altitude record for a non-rocket-propelled aircraft at 29,524 metres (96,860 ft) in 2001. The Zephyr, developed by BAE Systems, is the latest in a line of record-breaking solar aircraft, making a 54-hour flight in 2007, and month-long flights are envisioned by 2010.

A solar balloon is a black balloon that is filled with ordinary air. As sunlight shines on the balloon, the air inside is heated and expands causing an upward buoyancy force, much like an artificially-heated hot air balloon. Some solar balloons are large enough for human flight, but usage is generally limited to the toy market as the surface-area to payload-weight ratio is relatively high.

Solar sails are a proposed form of spacecraft propulsion using large membrane mirrors to exploit radiation pressure from the Sun. Unlike rockets, solar sails require no fuel. Although the thrust is small compared to rockets, it continues as long as the Sun shines onto the deployed sail and in the vacuum of space significant speeds can eventually be achieved.

The High-altitude airship (HAA) is an unmanned, long-duration, lighter-than-air vehicle using helium gas for lift, and thin-film solar cells for power. The United States Department of Defense Missile Defense Agency has contracted Lockheed Martin to construct it to enhance the Ballistic Missile Defense System (BMDS). Airships have some advantages for solar-powered flight: they do not require power to remain aloft, and an airship's envelope presents a large area to the Sun.

Energy storage methods

Solar Two's thermal storage system generated electricity during cloudy weather and at night.Storage is an important issue in the development of solar energy because modern energy systems usually assume continuous availability of energy. Solar energy is not available at night, and the performance of solar power systems is affected by unpredictable weather patterns; therefore, storage media or back-up power systems must be used.

Thermal mass systems can store solar energy in the form of heat at domestically useful temperatures for daily or seasonal durations. Thermal storage systems generally use readily available materials with high specific heat capacities such as water, earth and stone. Well-designed systems can lower peak demand, shift time-of-use to off-peak hours and reduce overall heating and cooling requirements.

Phase change materials such as paraffin wax and Glauber's salt are another thermal storage media. These materials are inexpensive, readily available, and can deliver domestically useful temperatures (approximately 64 °C). The "Dover House" (in Dover, Massachusetts) was the first to use a Glauber's salt heating system, in 1948.

Solar energy can be stored at high temperatures using molten salts. Salts are an effective storage medium because they are low-cost, have a high specific heat capacity and can deliver heat at temperatures compatible with conventional power systems. The Solar Two used this method of energy storage, allowing it to store 1.44 TJ in its 68 m³ storage tank with an annual storage efficiency of about 99%.

Off-grid PV systems have traditionally used rechargeable batteries to store excess electricity. With grid-tied systems, excess electricity can be sent to the transmission grid. Net metering programs give these systems a credit for the electricity they deliver to the grid. This credit offsets electricity provided from the grid when the system cannot meet demand, effectively using the grid as a storage mechanism.

Pumped-storage hydroelectricity stores energy in the form of water pumped when energy is available from a lower elevation reservoir to a higher elevation one. The energy is recovered when demand is high by releasing the water to run through a hydroelectric power generator.

Development, deployment and economics

Nellis Solar Power Plant, the largest photovoltaic power plant in North AmericaBeginning with the surge in coal use which accompanied the Industrial Revolution, energy consumption has steadily transitioned from wood and biomass to fossil fuels. The early development of solar technologies starting in the 1860s was driven by an expectation that coal would soon become scarce. However development of solar technologies stagnated in the early 20th century in the face of the increasing availability, economy, and utility of coal and petroleum.

The 1973 oil embargo and 1979 energy crisis caused a reorganization of energy policies around the world and brought renewed attention to developing solar technologies. Deployment strategies focused on incentive programs such as the Federal Photovoltaic Utilization Program in the US and the Sunshine Program in Japan. Other efforts included the formation of research facilities in the US (SERI, now NREL), Japan (NEDO), and Germany (Fraunhofer Institute for Solar Energy Systems ISE).

Between 1970 and 1983 photovoltaic installations grew rapidly, but falling oil prices in the early 1980s moderated the growth of PV from 1984 to 1996. Since 1997, PV development has accelerated due to supply issues with oil and natural gas, global warming concerns (see Kyoto Protocol), and the improving economic position of PV relative to other energy technologies. Photovoltaic production growth has averaged 40% per year since 2000 and installed capacity reached 10.6 GW at the end of 2007. Since 2006 it has been economical for investors to install photovoltaics for free in return for a long term power purchase agreement. 50% of commercial systems were installed in this manner in 2007 and it is expected that 90% will by 2009. Nellis Air Force Base is receiving photoelectric power for about 2.2 ¢/kWh and grid power for 9 ¢/kWh.

Commercial solar water heaters began appearing in the United States in the 1890s. These systems saw increasing use until the 1920s but were gradually replaced by cheaper and more reliable heating fuels. As with photovoltaics, solar water heating attracted renewed attention as a result of the oil crises in the 1970s but interest subsided in the 1980s due to falling petroleum prices. Development in the solar water heating sector progressed steadily throughout the 1990s and growth rates have averaged 20% per year since 1999. Although generally underestimated, solar water heating is by far the most widely deployed solar technology with an estimated capacity of 154 GW as of 2007.

Commercial concentrating solar power (CSP) plants were first developed in the 1980s. CSP plants such as SEGS project in the United States have a LEC of 12-14 ¢/kWh. The 11 MW PS10 power tower in Spain, completed in late 2005, is Europe's first commercial CSP system, and a total capacity of 300 MW is expected to be installed in the same area by 2013.

Solar installations in recent years have also largely begun to expand into residential areas, with governments offering incentive programs to make "green" energy a more economically viable option. In Canada the government offers the RESOP (Renewable Energy Standard Offer Program). The program allows residential homeowners with solar panel installations to sell the energy they produce back to the grid (i.e., the government) at 41¢/kWh, while drawing power from the grid at an average rate of 20¢/kWh (see feed-in tariff). The program is designed to help promote the government's green agenda and lower the strain often placed on the energy grid at peak hours. With the incentives offered by the program the average payback period for a residential solar installation (sized between 1.3 kW and 5 kW) is estimated at 18 to 23 years, considering such cost factors as parts, installation and maintenance, as well as the average energy production of a system on an annual basis.

Daniel Lincot, the chairman of the 2008 European Photovoltaic Solar Energy Conference and the research director of the Paris-based Photovoltaic Energy Development and Research Institute, said that photovoltaics can cover all the world energy demand. Photovoltaics are 85 times as efficient as growing corn for ethanol. On a 300 feet by 300 feet (1 hectare) plot of land enough ethanol can be produced to drive a car 30,000 miles (48,000 km) per year or 2,500,000 miles (4,020,000 km) by covering the same land with photo cells.

Solar forge

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A solar forge is a device that uses the power of the sun to melt materials, such as asphalt. A large Fresnel lens, usually rectangular and several feet long on each side, is positioned as a lid of a hollow standing cylinder. The lens focuses the sun's radiation to a point inside the cylinder, where the material to be melted is placed. The effect is the same as a magnifying glass used to burn a dry leaf, except that the heat achieved is much greater.

Solar forges work best in desert areas where there is plenty of sunlight. They are dangerous to approach because they intensely concentrate heat and light from the sun. A safe way to handle the danger is to cover the lens when not in use. Solar forges are easy to build, because they consist of only two parts. Other optional parts are: a cover, a pollution-control device (for the smoke), a vent, a temperature gauge, protective fire-proof clothing, and gas masks. Solar forges have the benefit of cheap construction and no fuel cost, unlike other forges.

Solar hot water

Solar hot water panels for heating a swimming pool in the NetherlandsSolar hot water is water heated by the use of solar energy. Solar heating systems are generally composed of solar thermal collectors, a fluid system to move the heat from the collector to its point of usage. The system may use electricity for pumping the fluid, and have a reservoir or tank for heat storage and subsequent use. The systems may be used to heat water for a wide variety of uses, including home, business and industrial uses. Heating swimming pools, underfloor heating or energy input for space heating are more specific examples.

In many climates, a solar heating system can provide up to 85% of domestic hot water energy. In many northern European countries, combined hot water and space heating systems (solar combisystems) are used to provide 15 to 25% of home heating energy.

In the southern regions of Africa like Zimbabwe, solar water heaters have been gaining popularity, thanks to the Austrian- and other EU-funded projects that are promoting more environmentally friendly water heating solutions.

Residential solar thermal installations can be subdivided into two kinds of systems: compact and pumped systems. Both typically include an auxiliary energy source (electric heating element or connection to a gas or fuel oil central heating system) that is activated when the water in the tank falls below a minimum temperature setting such as 50 °C. Hence, hot water is always available. The combination of solar hot water heating and using the back-up heat from a wood stove chimney to heat water can enable a hot water system to work all year round in cooler climates without the supplemental heat requirement of a solar hot water system being met with fossil fuels or electricity.

Among pumped options, there is an important distinction to be made regarding the sustainability of the design of the system. This relates to what source of energy powers the pump and its controls. The type of pumped solar thermal systems which use mains electricity to pump the fluid through the panels are called low carbon solar because the pumping negates the carbon savings of the solar by about 20%, according to data in a report called "Side by side testing of eight solar water heatings" by DTI UK. However, zero-carbon pumped solar thermal systems use solar electricity which is generated onsite using photovoltaics to pump the fluid and to operate its control electronics. This represents a zero operational carbon footprint and is becoming an important design goal for innovative solar thermal systems.

Solar History

Flat-plate collectors for solar water heating were popular in Florida and Southern California in the 1920s. Due to the abundance of sunlight in Israel, solar water heaters were used by some 20% of the population by 1967. Following the energy crisis in the 1970s, the Israeli Knesset passed a law requiring the installation of solar water heaters in all new homes (except high towers with insufficient roof area). As a result, Israel is now the world leader in the use of solar energy per capita (3% of the primary national energy consumption).

During this time, there was some resurgence of interest in solar heating in North America. Technical innovation has improved performance, life expectancy and ease of use of these systems. Installation of solar hot water heating has become the norm in countries with an abundance of solar radiation, like Cyprus, Israel and Greece, as well as in Japan and Austria, where there is less.

Solar hot water systems have become popular in China, where basic models start at around 1,500 yuan (US$190), much cheaper than in Western countries (around 80% cheaper for a given size of collector). It is said that at least 30 million Chinese households now have one, and that the popularity is due to the efficient evacuated tubes which allow the heaters to function even under gray skies and at temperatures well below freezing.

In 2005, Spain became the first country in the world to require the installation of photovoltaic electricity generation in new buildings, and the second (after Israel) to require the installation of solar hot water systems.

Solar Usage

Hot water heated by the sun can be used to:

Heat water (e.g. for sanitary purposes such as showering, washing, ...)

Generate electricity

Designs suitable for hot climates can be much simpler and cheaper, and can be considered an appropriate technology for these places. The global solar thermal market is dominated by China, Europe, Japan and India.

Solar water heaters lower the cost of electric bills. A typical consumer can save about 30%-50% on his or her electric bill, while lessening the use of oil and the impact on the environment.

The typical 50 gallon electric water heater uses 11.1 barrels of oil a year, which translates into the same amount oil used by a typical 4 door sedan driven by the average consumer.

Electric utility companies often provide electricity by burning and releasing energy from unclean fuels such as oil and coal. Nuclear energy with no permanent nuclear waste disposal is often used. An electrical home hot water heater sits on an electrical grid and may be driving the use of unclean fuels on the other end of the grid.

Solar Technique

A thermodynamic water heater installed on a house in BelgiumIn order to heat water using solar energy, a collector is fastened to the roof of a building, or on a wall facing the sun. In some cases, the collector may be free-standing. The working fluid is either pumped (active system) or driven by natural convection (passive system) through it.

The collector could be made of a simple glass topped insulated box with a flat solar absorber made of sheet metal attached to copper pipes and painted black, or a set of metal tubes surrounded by an evacuated (near vacuum) glass cylinder. In some cases, before the solar energy is absorbed, a parabolic mirror is used to concentrate sunlight on the tube. Some systems are capable of converting light to heat and therefore are not as reliant on outside temperature.

A simple water heating system would pump cold water out to a collector to be heated, the heated water flows back to a collection tank. This type of collector can provide enough hot water for an entire family.

Heat is stored in a hot water tank. The volume of this tank will be larger with solar heating systems in order to allow for bad weather, and because the optimum final temperature for the absorber is lower than a typical immersion or combustion heater.

The working fluid for the absorber may be the hot water from the tank, but more commonly (at least in pumped systems) is a separate loop of fluid containing anti-freeze and a corrosion inhibitor which delivers heat to the tank through a heat exchanger (commonly a coil of copper tubing within the tank). Another lower-maintenance concept is the 'drain-back': no anti-freeze is required; instead all the piping is sloped to cause water to drain back to the tank. The tank is not pressurized and is open to atmospheric pressure. As soon as the pump shuts off, flow reverses and the pipes empty by the time when freezing could occur.

When a solar hot water and hot-water central heating system are used in conjunction, solar heat will either be concentrated in a pre-heating tank that feeds into the tank heated by the central heating, or the solar heat exchanger will be lower in the tank than the hotter one. However, the main need for central heating is at night when there is no sunlight and in winter when solar gain is lower. Therefore, solar water heating for washing and bathing is often a better application than central heating because supply and demand are better matched.

The water from the collector can reach very high temperatures in good sunshine, or if the pump fails. Designs should allow for relief of pressure and excess heat through a heat dump.

Solar Economics, energy and system costs

In sunny, warm locations, where freeze protection is not necessary, a batch type solar hot water heater can be extremely cost effective. In higher latitudes, there are often additional design requirements for cold weather, which add to system complexity. This has the effect of increasing the initial cost (but not the life-cycle cost) of a solar hot water system, to a level much higher than a comparable hot water heater of the conventional type. When calculating the total cost to own and operate, a proper analysis will consider that solar energy is free, thus greatly reducing the operating costs, whereas other energy sources, such as gas and electricity, can be quite expensive over time. Thus, when the initial costs of a solar system are properly financed and compared with energy costs, then in many cases the total monthly cost of solar heat can be less than other more conventional types of hot water heaters (and also in conjunction with an existing hot water heater). In addition, federal and local incentives can be significant.

As an example, a 56 ft.2 solar water heater can cost US $7,500, but that initial cost is reduced to just $3,300 in the US State of Oregon due to federal and state incentives. The system will save approximately US $230 per year, with a payback of 14 years. Lower payback periods are possible based on maximizing sun exposure. As energy prices rise, payback periods decrease. In cooler locations, solar heating used to be less efficient. Usable amounts of domestic hot water were only available in the summer months, on cloudless days, between April and October. During the winter and on cloudy days, the output was poor. Independent surveys have shown that modern systems do not suffer these limitations. There are cases of households in cool climates getting all of their domestic hot water year round from solar alone. Systems have been show to efficiently work as far north as Whitehorse, Yukon (latitude of 60 B 43' N ).

The installation costs in the UK used to be prohibitive, on average about £9,000. This is reduced in more recent years to £3,000, with payback period reduced, with the rise in the gas price, to 12 years. As energy prices rise, payback periods shorten accordingly.

According to ANRE (a Flemish energy agency, subsidised by the Flemish or Belgian government, a complete, commercial (active) solar hot water system composed of a solar collector (3-4 m²; this is large enough for 4 people), pipes and tank (again large enough for 4 people) costs around 4000 euro. The installation by a recognised worker costs another 800 euro. Electrabel's home magazine Eandismagazine stated in 2008 that a complete system (including 4m2 of solar collectors and a supply barrel of 200-240 liters) to cost 4500 euro. The system would then pay back itself in 11 years , when the returns are weighed off against a regular electric boiler. Calculation was as follows: a saving of 1875 kWh (which is 50% of the energy requirements in domestic hot water production) x 0.10 euro/kWh = 187, 5 euros. This multiplied by 11.6 years made 2175 euros (or the cost of the system with deducted regional tax benefits).

In Australia, the cost for an average solar hot water system fully installed is between $1,800 and $2,800. This is after tax rebates (there is a federal rebate, some state rebates and Renewable Energy Certificates). According to the Department of Environment and Water Resources, the yearly electricity savings are between $300 and $700. This brings the payback period to under 2 years in the best case and under 10 years in the worst case.

Solar Types

Solar hot water systems can be classified in different ways:

The type of collector used (see below)

The location of the collector - roof mount, ground mount, wall mount

The location of the storage tank in relation to the collector

The requirement for a pump - active vs. passive

The method of heat transfer - open-loop or closed-loop (via heat exchanger)

Compact Solar systems (passive systems)

A DIY batch solar heaterA passive system also known as a monobloc (thermosiphon) system, a compact system consists of a tank for the heated water, a solar collector, and connecting pipes all pre-mounted in a frame. The water flows upward when heated in the panel. When this water enters the tank (positioned higher than the solar panel), it expels some cold water from inside so that the heat transfer takes place without the need for a pump. A typical system for a four-person home in a sunny region consists of a tank of 150 to 300 litres (36.9 to 79.2 gallons) and three to four square metres of solar collector panels.

A special type of compact system is the Integrated Collector Storage (ICS or Batch Heater) where the tank acts as both storage and solar collector. Batch heaters are basically thin rectilinear tanks with glass in front of it generally in or on house wall or roof. They are seldom pressurised and usually depend on gravity flow to deliver their water. They are simple, efficient and less costly than intense plate and tube collectors but only suitable in moderate climates with good sunshine. A step up from the ICS is the Convection Heat Storage Unit. These are plate type intense collectors with build-in insulated tank. The unit uses convection (movement of hot water upward) to move the water from heater to tank. Neither pumps or electricity are used. It is more efficient than a ICS as the intense collector heats a small(er) amount of water that is constantly rising to the tank. It can be used in areas with less sunshine than the ICS.

Another system is the Copper Cricket. The Copper Cricket is a special system which can be implemented into a existing (eg electric) hot water heater. It is manufactured by companies such as Sage Advance Corporation. The device works without any pumps or electricity.

Direct ('open loop') compact systems, if made of metals are not suitable for cold climates. At night the remaining water can freeze and damage the panels, and the storage tank is exposed to the outdoor temperatures that will cause excessive heat losses on cold days. Some compact systems have a primary circuit. The primary circuit includes the collectors and the external part of the tank. Instead of water, a non-toxic antifreeze is used. When this liquid is heated up, it flows to the external part of the tank and transfers the heat to the water placed inside. ('closed loop'). However, direct ('open loop') systems are slightly cheaper and more efficient.

A compact system can save up to 4.5 tonnes annually of greenhouse gas emissions. In order to achieve the aims of the Kyoto Protocol, several countries are offering subsidies to the end user. Some systems can work for up to 25 years with minimum maintenance. These kinds of systems can be redeemed in six years, and achieve a positive balance of energy (energy used to build them minus energy they save) of 1.5 years. Most part of the year, when the electric heating element is not working, these systems do not use any external source for power (as water flows due to thermosyphon principle).

Flat solar thermal collectors are usually used, but compact systems using vacuum tube collectors are available on the market. These generally give a higher heat yield per square meter in colder climates but cost more than flat plate collector systems.

Pumped Solar systems (active systems)

How the solar water heating system is pumped and controlled determines whether it is a zero carbon or a low carbon system. Low carbon systems principally use electricity to circulate the fluid through the collector. The use of electricity typically reduces the carbon savings of a system by 10% to 20%.

Conventional low carbon system designs use a mains powered circulation pump whenever the hot water tank is positioned below the solar panels. Most systems in northern Europe are of this type. The storage tank is placed inside the building, and thus requires a controller that measures when the water is hotter in the panels than in the tank. The system also requires a pump for transferring the fluid between the parts.

The electronic controllers used by some systems permit a wide range of functionality such as measurement of the energy produced; more sophisticated safety functions; thermostatic and time-clock control of auxiliary heat, hot water circulation loops, or others; display or transfer of error messages or alarms; remote display panels; and remote or local datalogging.

Newer zero carbon solar water heating systems are powered by solar electric (photovoltaic or PV) pumps. These typically use a 5-20W PV panel which faces in the same direction as the main solar heating panel and a small, low flow diaphragm pump to pump the water.

The most commonly used solar collector is the insulated glazed flat panel. Less expensive panels, like polypropylene panels (for swimming pools) or higher-performing ones like evacuated tube collectors, are sometimes used.

Types of Solar thermal collector

It has been suggested that this article or section be merged into Solar thermal collector. (Discuss)

There are three main kinds of solar thermal collectors in common use. In order of increasing cost they are: Formed Plastic Collectors, Flat Collectors, and Evacuated Tube Collectors. The efficiency of the system is directly related to heat losses from the collector surface (efficiency being defined as the proportion of heating energy that can be usefully obtained from insulation). Heat losses are predominantly governed by the thermal gradient between the temperature of the collector surface and the ambient temperature. Efficiency decreases when either the ambient temperature falls or as the collector temperature increases. This decrease in efficiency can be mitigated by increasing the insulation of the unit by sealing the unit in glass e.g. flat collectors or providing a vacuum seal e.g. evacuated tube collector. The choice of collector is determined by the heating requirements and environmental conditions in which it is employed.

Formed Solar plastic collector

Formed plastic collectors (such as polypropylene, EPDM or PET plastics) consist of tubes or formed panels through which water is circulated and heated by the sun's radiation. These are often used for extending the swimming season in swimming pools. In some countries, heating an open-air swimming pool with non-renewable energy sources is not allowed, and then these inexpensive systems offer a good solution. This panel is not suitable for year-round uses like providing hot water for home use, primarily due to its lack of insulation which reduces its effectiveness greatly when the ambient air temperature is lower than the temperature of the fluid being heated.

Flat plate Solar collector

A flat plate collector consists of a thin absorber sheet (of thermally stable polymers, aluminum, steel or copper, to which a black or selective coating is applied) backed by a grid or coil of fluid tubing and placed in an insulated casing with a glass or polycarbonate cover.

Fluid is circulated, using either mains or solar electricity, through the tubing to remove the heat from the absorber and to transport it to an insulated water tank, sometimes directly or otherwise to a heat exchanger or to some other device for using the heated fluid. Some fabricants have a completely flooded absorber consisting of 2 sheets of metal stamped to produce a circulation zone. Because the heat exchange area is greater they may be marginally more efficient than traditional absorbers.

As an alternative to metal collectors, new polymer flat plate collectors are now being produced in Europe. These may be wholly polymer, or they may be metal plates behind which are freeze-tolerant water channels made of silicone rubber instead of metal. Polymers, being flexible and therefore freeze-tolerant, are able to contain plain water instead of antifreeze, so that in some cases they are able to plumb directly into existing water tanks instead of needing the tank to be replaced with one using heat exchangers. By dispensing with a heat exchanger in these flat plate panel, temperatures need not be quite so high for the circulation system to be switched on, so such direct circulation panels, whether polymer or otherwise, can be somewhat more efficient, particularly at low light levels.

As with evacuated tubes, most flat plate collectors have a life expectancy of over 25 years.

Evacuated Solar tube collector

Evacuated (or vacuum) tubes panel.Evacuated tube collectors are made of a series of modular tubes, mounted in parallel, whose number can be added to or reduced as hot water delivery needs change. This type of collector consists of rows of parallel transparent glass tubes, each of which contains an absorber tube (in place of the absorber plate to which metal tubes are attached in a flat-plate collector). The tubes are covered with a special light-modulating coating. In an evacuated tube collector, sunlight passing through an outer glass tube heats the absorber tube contained within it. The absorber can either consist of copper (glass-metal) or specially-coated glass tubing (glass-glass). The glass-metal evacuated tubes are typically sealed at the manifold end, and the absorber is actually sealed in the vacuum, thus the fact that the absorber and heat pipe are dissimilar metals creates no corrosion problems. The better quality systems use foam insulation in the manifold. low iron glass is used in the higher quality evacuated tubes manufacture.

Lower quality evacuated tube systems use the glass coated absorber. Due to the extreme temperature difference of the glass under stagnation temperatures, the glass sometimes shatters. The glass is a lower quality boron silicate material and the aluminum absorber and copper heat pipe are slid down inside the open top end of the tube. Moisture entering the manifold around the sheet metal casing is eventually absorbed by the glass fibre insulation and then finds its way down into the tubes. This leads to corrosion at the absorber/heat pipe interface area, also freeze ruptures of the tube itself if the tube fills sufficiently with water.

Two types of tube collectors are distinguished by their heat transfer method: the simplest pumps a heat transfer fluid (water or antifreeze) through a U-shaped copper tube placed in each of the glass collector tubes. The second type uses a sealed heat pipe that contains a liquid that vapourises as it is heated. The vapour rises to a heat-transfer bulb that is positioned outside the collector tube in a pipe through which a second heat transfer liquid (the water or antifreeze) is pumped. For both types, the heated liquid then circulates through a heat exchanger and gives off its heat to water that is stored in a storage tank (which itself may be kept warm partially by sunlight). Evacuated tube collectors heat to higher temperatures, with some models providing considerably more solar yield per square metre than flat panels. However, they are more expensive and fragile than flat panels. Evacuated heat tubes perform better than flat plate collectors in cold climates because they only rely on the light they receive and not the outside temperature. The high stagnation temperatures can cause antifreeze to break down, so careful consideration must be used if selecting this type of system in temperate climates.Tubes come in different levels of quality so the different kinds have to be examined as well. High quality units can efficiently absorb diffuse solar radiation present in cloudy conditions and are unaffected by wind. They also have the same performance in similar light conditions summer and winter.

For a given absorber area, evacuated tubes can maintain their efficiency over a wide range of ambient temperatures and heating requirements. The absorber area only occupied about 50% of the collector panel on early designs, however this has changed as the technology has advanced to maximize the absorption area. In extremely hot climates, flat-plate collectors will generally be a more cost-effective solution than evacuated tubes. When employed in arrays of 20 to 30 or more, the efficient but costly evacuated tube collectors have net benefit in winter and also give real advantage in the summer months. They are well suited to extremely cold ambient temperatures and work well in situations of consistently low-light. They are also used in industrial applications, where high water temperatures or steam need to be generated. Properly designed evacuated tubes have a life expectancy of over 25 years which greatly adds to their value.

Solar thermal cooling

Solar thermal cooling can be achieved via absorption refrigeration cycles, desiccant cycles and solar-mechanical processes.

The absorption cycle solar cooling system works like a refrigerator in that it uses hot water to compress a gas that, once expanded, will absorb energy, which cools the air. The main problem currently is that the absorber machine works with liquid at 90 °C, a fairly high temperature to be reached with pumped solar panels with no auxiliary power supply.

The same pumped solar thermal installation can be used for producing hot water for the whole year. It can also be used for cooling in the summer and partially heating the building in winter.

DIY Solar systems

With an ever-rising do-it-yourself-community and their increasing environmental awareness, people have begun building their own (small-scale) solar hot water systems from scratch or buying easy to install kits. Plans for solar hot water systems are available on the Internet. and people have sprung up building them for their own domestic requirements. DIY solar hot water systems are usually much cheaper than commercial ones, and installation costs can sometimes be avoided as well. The DIY-solar hot water systems are being used both in the developed world, as in the developing world, to generate hot water. Rather than build systems from scratch, many DIY solar enthusiasts are buying simple off-the-shelf solar DIY kits. In particular the new freeze tolerant, zero-carbon PV pumped systems, are becoming common in parts of Europe, since their simplicity enables them to be plumbed in quickly and safely without the need of a mains electrician.

Solar water disinfection

SODIS application in IndonesiaSolar water disinfection, also known as SODIS is a method of disinfecting water using only sunlight and plastic PET bottles. SODIS is a cheap and effective method for decentralized water treatment, usually applied at the household level and is recommended by the World Health Organization as a viable method for household water treatment and safe storage. SODIS is already applied in numerous developing countries.

Solar Principle

Exposure to sunlight has been shown to deactivate diarrhea-causing organisms in polluted drinking water. Three effects of solar radiation are believed to contribute to the inactivation of pathogenic organisms:

UV-A interferes directly with the metabolism and destroys cell structures of bacteria.

UV-A (wavelength 320-400nm) reacts with oxygen dissolved in the water and produces highly reactive forms of oxygen (oxygen free radicals and hydrogen peroxides), that are believed to also damage pathogens.

Infrared radiation heats the water. If the water temperatures raises above 50°C, the disinfection process is three times faster.

At a water temperature of about 30°C (86°F), a threshold solar radiation intensity of at least 500 W/m2 (all spectral light) is required for about 5 hours for SODIS to be efficient. This dose contains energy of 555 Wh/m2 in the range of UV-A and violet light, 350nm-450nm, corresponding to about 6 hours of mid-latitude (European) midday summer sunshine.

At water temperatures higher than 45°C (113°F), synergetic effects of UV radiation and temperature further enhance the disinfection efficiency.

Solar Guidelines for the application at household level

Water from contaminated sources are filled into transparent water bottles. For oxygen saturation, bottles can be filled three quarters, then shaken for 20 seconds (with the cap on), then filled completely. Highly turbid water (turbidity higher than 30 NTU) must be filtered prior to exposure to the sunlight.

Filled bottles are then exposed to the sun. Better temperature effects can be achieved if bottles are placed on a corrugated roof as compared to thatched roofs.

The treated water can be consumed. The risk of re-contamination can be minimized if water is stored in the bottles. The water should be consumed directly from the bottle or poured into clean drinking cups. Re-filling and storage in other containers increases the risk of contamination.

Suggested Treatment Schedule Weather Conditions Minimum Treatment Duration

sunny 6 hours

50% cloudy 6 hours

50-100% cloudy 2 days

continuous rainfall unsatisfactory performance, use rainwater harvesting

Applications of Solar SODIS

SODIS is an effective method for treating water where fuel or cookers are unavailable or prohibitively expensive. Even where fuel is available, SODIS is a more economical and environmentally friendly option. The application of SODIS is limited if enough bottles are not available, or if the water is highly turbid.

In theory, the method could be used in disaster relief or refugee camps. However, supplying bottles may be more difficult than providing equivalent disinfecting tablets containing chlorine, bromine, or iodine. Additionally, in some circumstances, it may be difficult to guarantee that the water will be left in the sun for the necessary time.

Other methods for household water treatment and safe storage exist, e.g. chlorination, different filtration procedures or flocculation/disinfection. The selection of the adequate method should be based on the criteria of effectiveness, the co-occurrence of other types of pollution (turbidity, chemical pollutants), treatment costs, labor input and convenience, and the user’s preference.

Solar Cautions

If the water bottles are not left in the sun for the proper length of time, the water may not be safe to drink and could cause illness. If the sunlight is less strong, due to overcast weather or a less sunny climate, a longer exposure time in the sun is necessary.

The following issues should also be considered:

Bottle material: Some glass or PVC materials may prevent ultraviolet light from reaching the water. Commercially available bottles made of PET are recommended. The handling is much more convenient in the case of PET bottles. Polycarbonate blocks all UVA and UVB rays, and therefore should not be used. Glass also blocks UV rays and therefore would be ineffective.

Aging of plastic bottles: SODIS efficiency depends on the physical condition of the plastic bottles, with scratches and other signs of wear reducing the efficiency of SODIS. Heavily scratched or old, blind bottles should be replaced. Shape of Containers: the intensity of the UV radiation decreases rapidly with increasing water depth. At a water depth of 10cm and moderate turbidity of 26 NTU, UV-A radiation is reduced to 50%. PET soft drink bottles are often easily available and thus most practical for the SODIS application.

Oxygen: Sunlight produces highly reactive forms of oxygen (oxygen free radicals and hydrogen peroxides) in the water. These reactive molecules contribute in the destruction process of the microorganisms. Under normal conditions (rivers, creeks, wells, ponds, tap) water contains sufficient oxygen (more than 3 mg Oxygen per litre) and does not have to be aerated before the application of SODIS.

Leaching of bottle material: There has been some concern over the question whether plastic drinking containers can release chemicals or toxic components into water, a process possibly accelerated by heat. The Swiss Federal Laboratories for Materials Testing and Research have examined the diffusion of adipates and phthalates (DEHA and DEHP) from new and reused PET-bottles in the water during solar exposure. The levels of concentrations found in the water after a solar exposure of 17 hours in 60°C water were far below WHO guidelines for drinking water and in the same magnitude as the concentrations of phthalate and adipate generally found in high quality tap water. Concerns about the general use of PET-bottles were also expressed after a report published by researchers from the University of Heidelberg on antimony being released from PET-bottles for soft drinks and mineral water stored over several months in supermarkets. However, the antimony concentrations found in the bottles are orders of magnitude below WHO and national guidelines for antimony concentrations in drinking water. Furthermore, SODIS water is not stored over such extended periods in the bottles.

Solar Health impact, diarrhea reduction It has been shown that the SODIS method (and other methods of household water treatment) can very effectively remove pathogenic contamination from the water. However, infectious diseases are also transmitted through other pathways, i.e. due to a general lack of sanitation and hygiene. Studies on the reduction of diarrhea among SODIS users show reduction values of 30-80%.

Solar SODIS research and development

The effectiveness of the SODIS was first discovered by Professor Aftim Acra at the American University of Beirut in the early 1980s. Substantial follow-up research was conducted by the research groups of Martin Wegelin at the Swiss Federal Institute of Aquatic Science and Technology (Eawag) and Dr Kevin McGuigan at the Royal College of Surgeons in Ireland. Clinical control trials were pioneered by Professor Ronan Conroy of the RCSI team in collaboration with Dr T Michael Elmore-Meegan.

Currently, a joint research project on SODIS is implemented by the following institutions:

Royal College of Surgeons in Ireland (RCSI), Ireland (coordination)

University of Ulster (UU), United Kingdom

CSIR Environmentek, South Africa, Eawag, Switzerland

The Institute of Water and Sanitation Development (IWSD), Zimbabwe

Plataforma Solar de Almería (CIEMAT-PSA), Spain

University of Leicester (UL), United Kingdom

The International Commission for the Relief of Suffering & Starvation (ICROSS), Kenya

University of Santiago de Compostela (USC), Spain

Swiss Federal Institute of Aquatic Science and Technology (Eawag), Switzerland

The project has embarked on a multi-country study including study areas in Zimbabwe, South Africa and Kenya.

Other developments include a continuous flow disinfection unit and solar disinfection with titanium dioxide film over glass cylinders which prevents the bacterial regrowth of coliforms after SODIS. Research has shown that a number of low-cost additives are capable of accelerating SODIS and that additives might make SODIS more rapid and effective in both sunny and cloudy weather, developments that could help make the technology more effective and acceptable to users. Another study showed that natural coagulants (seeds of five natural plant species--Vigna unguiculata, Phaseolus mungo, Glycine max, Pisum sativam, and Arachis hypogea--were evaluated for the removal of turbidity), were as effective as commercial alum and even superior for clarification because the optimum dosage was low.

Worldwide application of Solar SODIS

The Swiss Federal Institute of Aquatic Science and Technology (Eawag), through the Department of Water and Sanitation in Developing Countries (Sandec), coordinates SODIS promotion projects in 33 countries including Bhutan, Bolivia, Burkina Faso, Cambodia, Cameroon, DR Congo, Ecuador, El Salvador, Ethiopia, Ghana, Guatemala, Guinea, Honduras, India, Indonesia, Kenya, Laos, Malawi, Mozambique, Nepal, Nicaragua, Pakistan, Perú, Philippines, Senegal, Sierra Leone, Sri Lanka, Togo, Uganda, Uzbekistan, Vietnam, Zambia, and Zimbabwe. Contact addresses and case studies of the projects coordinated by the Swiss Federal Institute of Aquatic Science and Technology (Eawag) are available at sodis.ch.

SODIS projects are funded by, among others, the SOLAQUA Foundation, several Lions Clubs, Rotary Clubs, Migros, and the Michel Comte Water Foundation.

SODIS has also been applied in several communities in Brazil, one of them being Prainha do Canto Verde north of Fortaleza. There, the villagers have been purifying their water with the SODIS method. It is quite successful, especially since the temperature during the day can go beyond the 40°C (100°F) and there is a limited amount of shade.